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Structure and properties of Pd–Mn hexaaluminate catalysts modified with platinum for the high-temperature oxidation of methane

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Abstract

The effect of Pt additives on the catalytic characteristics of a Pd-containing catalyst based on manganese hexaaluminate was studied. It was found that the bimetallic PtPd-containing catalysts based on MnLaAl11O19 with the Pt/Pd atomic ratio smaller than 0.25 exhibited a comparable or somewhat smaller activity in the methane oxidation, but their stability at elevated temperatures and gas flow rates was higher than that of the Pd-based catalyst. The state of the active constituent of the resulting catalysts was investigated. Main correlations between the state of the active component and the catalytic activity were revealed.

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References

  1. US Patent 6015285, 2000.

  2. Parmon, V.N., Ismagilov, Z.R., Favorskii, O.N., Belokon’, A.A., and Zakharov, V.M., Izv. Ross. Akad. Nauk, Ser. Khim., 2007, vol. 77, p. 819.

    CAS  Google Scholar 

  3. Lampert, J.K., Kazi, M.S., and Farrauto, R.J., Appl. Catal., B, 1997, vol. 14, p. 21.

    Article  Google Scholar 

  4. Hicks, R.F., Qi, H., Young, M.L., and Lee, R.G., J. Catal., 1990, vol. 122, p. 280.

    Article  CAS  Google Scholar 

  5. Hicks, R.F., Qi, H., Young, M.L., and Lee, R.G., J. Catal., 1990, vol. 122, p. 295.

    Article  CAS  Google Scholar 

  6. Burch, R., Appl. Catal., 1990, vol. 66, p. 337.

    Article  Google Scholar 

  7. Burch, R., Appl. Catal., 1990, vol. 66, p. 359.

    Article  Google Scholar 

  8. Yashnik, S.A., Ismagilov, Z.R., Kuznetsov, V.V., Ushakov, V.V., Rogov, V.A., and Ovsyannikova, I.A., Catal. Today, 2006, vol. 117, p. 525.

    Article  CAS  Google Scholar 

  9. McCarty, J.G., Gusman, M., Lowe, D.M., Hildenbrand, D.L., and Lau, K.N., Catal. Today, 1999, vol. 47, p. 5.

    Article  CAS  Google Scholar 

  10. Pfefferle, L.D. and Pfefferle, W.C., Catal. Rev. Sci. Eng., 1987, vol. 29, p. 219.

    Article  CAS  Google Scholar 

  11. Lyubovsky, M. and Pfefferle, L.D., Appl. Catal., A, 1998, vol. 173, p. 107.

    Article  CAS  Google Scholar 

  12. Ismagilov, Z.R., Kerzhentsev, M.A., Yashnik, S.A., Shikina, N.V., Zagoruiko, A.N., Parmon, V.N., Zakharov, V.M., Braynin, B.I., and Favorski, O.N., Gas Turbines, Gurrapa, I., Ed., Rijeka, Croatia: Sciyo, 2010, p. 79.

    Google Scholar 

  13. Ismagilov, Z.R., Kerzhentsev, M.A., Sazonov, V.A., Tsykoza, L.T., Shikina, N.V., Kuznetsov, V.V., Ushakov, V.A., Mishanin, S.V., Kozhukhar, N.G., Russo, G., and Deutschmann, O., Korean J. Chem. Eng., 2003, vol. 20, p. 461.

    Article  CAS  Google Scholar 

  14. Sekizawa, K., Machida, M., Eguchi, K., and Arai, H., J. Catal., 1993, vol. 142, p. 655.

    Article  CAS  Google Scholar 

  15. Farrauto, R.J., Lampert, J.K., Hobson, M.C., and Waterman, E.M., Appl. Catal., B, 1995, vol. 6, p. 263.

    Article  CAS  Google Scholar 

  16. McCarty, J.G., Catal. Today, 1995, vol. 26, p. 283.

    Article  CAS  Google Scholar 

  17. Salomonsson, P., Johansson, S., and Kasemo, B., Catal. Lett., 1995, vol. 33, p. 1.

    Article  CAS  Google Scholar 

  18. Yashnik, S.A. and Ismagilov, Z.R., Top. Catal., 2012, vol. 55, p. 818.

    Article  CAS  Google Scholar 

  19. Burch, R., Urbano, F.J., and Loader, P.K., Appl. Catal., A, 1995, vol. 123, p. 173.

    Article  CAS  Google Scholar 

  20. Ciuparu, D., Katsikis, N., and Pfefferle, L., Appl. Catal., A, 2001, vol. 216, p. 209.

    Article  CAS  Google Scholar 

  21. Mowery, D.L. and McCormick, R.L., Appl. Catal., B, 2001, vol. 34, p. 287.

    Article  CAS  Google Scholar 

  22. Thevenin, P.O., Ersson, A.G., Kusar, H.M.J., Menon, P.G., and Jaras, S.G., Appl. Catal., A, 2001, vol. 212, p. 189.

    Article  CAS  Google Scholar 

  23. Yamamoto, H. and Uchida, H., Catal. Today, 1998, vol. 45, p. 147.

    Article  CAS  Google Scholar 

  24. Persson, K., Ersson, A., Jansson, K., Iverlund, N., and Jaras, S., J. Catal., 2005, vol. 231, p. 139.

    Article  CAS  Google Scholar 

  25. Lapisardi, G., Urfels, L., Gelin, P., Primet, M., Kaddouri, A., Garbowski, E., Toppi, S., and Tena, E., Catal. Today, 2006, vol. 117, p. 564.

    Article  CAS  Google Scholar 

  26. Castellazzi, P., Groppi, G., and Forzatti, P., Appl. Catal., B, 2010, vol. 95, p. 303.

    Article  CAS  Google Scholar 

  27. Yashnik, S.A., Ismagilov, Z.R., Denisov, S.P., and Danchenko, N.M., 9th Int. Congr. on Catalysis and Automotive Pollution Control, Brussels, vol. 3, p. 349.

  28. Yashnik, S.A., Ismagilov, Z.R., and Danchenko, N.M., Appl. Catal., B, 2016, vol. 185, p. 322.

    Article  CAS  Google Scholar 

  29. Ismagilov, Z.R., Shikina, N.V., Yashnik, S.A., Parmon, V.N., Favorskii, O.N., Zakharov, V.M., and Branin, B.I., RF Patent 2372556, 2009.

    Google Scholar 

  30. Gulyaeva, Yu.K., Kaichev, V.V., Zaikovskii, V.I., Suknev, A.P., and Bal’zhinimaev, B.S., Appl. Catal., A, 2015, vol. 506, p. 197.

    Article  CAS  Google Scholar 

  31. Scofield, J.H., J. Electron Spectrosc. Relat. Phenom., 1976, vol. 8, p. 129.

    Article  CAS  Google Scholar 

  32. Fairley, N. http://www.casaxps.com

  33. Narui, K., Yataa, H., Furuta, K., Nishida, A., Kohtoku, Y., and Matsuzaki, T., Appl. Catal., A, 1999, vol. 179, p. 165.

    Article  CAS  Google Scholar 

  34. Pieck, C.L., Vera, C.R., Peirotti, E.M., and Yori, J.C., Appl. Catal., A, 2002, vol. 226, p. 281.

    Article  CAS  Google Scholar 

  35. Toebes, M.L., van Dillen, J.A., and de Jong, K.P., J. Mol. Catal. A: Chem., 2001, vol. 173, p. 75.

    Article  CAS  Google Scholar 

  36. Ismagilov, Z.R., Shikina, N.V., Yashnik, S.A., Zagoruiko, A.N., Khairulin, S.R., Kerzhentsev, M.A., Korotkikh, V.N., Parmon, V.N., Brainin, B.I., Zakharov, V.M., and Favorskii, O.N., Kinet. Catal., 2008, vol. 49, no. 6, p. 873.

    Article  CAS  Google Scholar 

  37. Yashnik, S.A., Shikina, N.V., Ismagilov, Z.R., Zagoruiko, A.N., Kerzhentsev, M.A., Parmon, V.N., Zakharov, V.M., Braynin, B.I., Favorski, O.N., and Gumerov, A.M., Catal. Today, 2009, vol. 147, p. 237.

    Article  Google Scholar 

  38. Mendialdua, J., Casanova, R., Rueda, F., Rodriguez, A., Quinones, J., Alarcon, L., Escalante, E., Hoffmann, P., Taebi, I., and Jalowiecki, L., J. Mol. Catal. A: Chem., 2005, vol. 228, p. 151.

    Article  CAS  Google Scholar 

  39. Kosova, N., Devyatkina, E., Slobodyuk, A., and Kaichev, V., Solid State Ionics, 2008, vol. 179, p. 1745.

    Article  CAS  Google Scholar 

  40. Pesty, H.-P., Zhang, L., and Madey, T.E., Phys. Rev. B: Condens. Matter, 1995, vol. 51, p. 2427.

    Article  Google Scholar 

  41. Bancroft, G.M., Adams, I., Coatsworth, L.L., Bennewitz, C.D., Brown, J.D., and Westwood, W.D., Anal. Chem., 1975, vol. 47, p. 586.

    Article  CAS  Google Scholar 

  42. Barr, T.L., J. Phys. Chem., 1978, vol. 82, p. 1801.

    Article  CAS  Google Scholar 

  43. Oku, M., Hirokawa, K., and Ikeda, S., J. Electron Spectrosc. Relat. Phenom., 1975, vol. 7, p. 465.

    Article  CAS  Google Scholar 

  44. Burroughs, P., Hammett, H., Orchard, A.F., and Thornton, J.T., J. Chem. Soc., Dalton Trans., 1976, vol. 17, p. 1686.

    Article  Google Scholar 

  45. Ledford, J.S., Houalla, M., Proctor, A., Gercules, D.M., and Petrakis, L., J. Phys. Chem., 1989, vol. 93, p. 6770.

    Article  CAS  Google Scholar 

  46. Shelef, M., Haack, L.P., Soltis, R.E., and Logothetis, E.M., J. Catal., 1992, vol. 137, p. 114.

    Article  CAS  Google Scholar 

  47. Ihm, S.-K., Jun, Y.-D., Kim, D.-C., and Jeong, K.-E., Catal. Today, 2004, vols. 93–95, p. 149.

    Article  Google Scholar 

  48. Monteiro, R.S., Zemlyanov, D., Storey, J.M., and Ribeiro, F.H., J. Catal., 2001, vol. 201, p. 37.

    Article  CAS  Google Scholar 

  49. Sun, K., Lu, W., Wang, M., and Xu, X., Appl. Catal., A, 2004, vol. 268, p. 107.

    Article  CAS  Google Scholar 

  50. Anumol, E.A., Halder, A., Nethravathi, C., Viswanath, B., and Ravishankar, N., J. Mater. Chem., 2011, vol. 21, p. 8721.

    Article  CAS  Google Scholar 

  51. Bonarowska, M., Pielaszek, J., Juszczyk, W., and Karpinski, J., J. Catal., 2000, vol. 195, p. 304.

    Article  CAS  Google Scholar 

  52. Burch, R. and Urbano, F.J., Appl. Catal., A, 1995, vol. 124, p. 121.

    Article  CAS  Google Scholar 

  53. Bonarowska, M., Pielaszek, J., Semikolenov, V.A., and Karpinski, Z., J. Catal., 2002, vol. 209, p. 528.

    Article  CAS  Google Scholar 

  54. Bonarowska, M. and Karpinski, Z., Catal. Today, 2008, vol. 137, p. 498.

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090, Russia

    S. A. Yashnik, T. A. Surovtsova, A. V. Ishchenko, V. V. Kaichev & Z. R. Ismagilov

  2. Institute of Coal Chemistry and Chemical Materials Science, Siberian Branch, Russian Academy of Sciences, Kemerovo, 650000, Russia

    Z. R. Ismagilov

Authors
  1. S. A. Yashnik
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  2. T. A. Surovtsova
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  3. A. V. Ishchenko
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  4. V. V. Kaichev
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  5. Z. R. Ismagilov
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Correspondence to S. A. Yashnik.

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Original Russian Text © S.A. Yashnik, T.A. Surovtsova, A.V. Ishchenko, V.V. Kaichev, Z.R. Ismagilov, 2016, published in Kinetika i Kataliz, 2016, Vol. 57, No. 4, pp. 535–547.

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Yashnik, S.A., Surovtsova, T.A., Ishchenko, A.V. et al. Structure and properties of Pd–Mn hexaaluminate catalysts modified with platinum for the high-temperature oxidation of methane. Kinet Catal 57, 528–539 (2016). https://doi.org/10.1134/S0023158416040157

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  • DOI: https://doi.org/10.1134/S0023158416040157

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