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Adsorption of molecular hydrogen on aluminophosphate zeolites at 77 K

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Abstract

The H2 sorption properties of the aluminophosphate zeolites AlPO-5, AlPO-31, AlPO-11, AlPO-36, and AlPO-8 at 77 K have been investigated. A series of H2 adsorption isotherms has been obtained for cylindrical micropore channels in the aluminophosphate zeolites. The absolute values of the amount adsorbed α(P) for the mesoporous aluminophosphate materials and the effective density of adsorbed H2 in the micropore space β*(P, d) have been determined. It has been demonstrated experimentally that the sorbate density depends on the size of the micropore channel of the zeolite d. Hydrogen sorption isotherms have been calculated from experimental isotherms. A procedure allowing β*(P, d) to be estimated for intermediate d values is presented.

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Authors and Affiliations

  1. Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090, Russia

    R. A. Shutilov, I. V. Grenev, O. V. Kikhtyanin & V. Yu. Gavrilov

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  1. R. A. Shutilov
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  2. I. V. Grenev
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  3. O. V. Kikhtyanin
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  4. V. Yu. Gavrilov
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Correspondence to V. Yu. Gavrilov.

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Original Russian Text © R.A. Shutilov, I.V. Grenev, O.V. Kikhtyanin, V.Yu. Gavrilov, 2012, published in Kinetika i Kataliz, 2012, Vol. 53, No. 1, pp. 141–149.

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Shutilov, R.A., Grenev, I.V., Kikhtyanin, O.V. et al. Adsorption of molecular hydrogen on aluminophosphate zeolites at 77 K. Kinet Catal 53, 137–144 (2012). https://doi.org/10.1134/S0023158412010119

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  • DOI: https://doi.org/10.1134/S0023158412010119

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