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Bimetallic Rh-Co/ZrO2 catalysts for ethanol steam reforming into hydrogen-containing gas

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Abstract

The properties of supported bimetallic Rh-Co/ZrO2 catalysts in ethanol steam reforming into hydrogen-containing gas were studied. The particles of Rh-Co solid solutions on the catalyst surface were prepared by the thermal decomposition of the double complex salt [Co(NH3)6][Rh(NO2)6] and the solid solution Na3[RhCo(NO2)6]. It was found that the bimetallic Rh-Co/ZrO2 catalysts exhibited high activity in the reaction of ethanol steam reforming. The equilibrium composition of reaction products was attained at 500–700°C and a reaction mixture space velocity of 10000 h−1.

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References

  1. Llorca, J., Homs, N., Sales, J., Fierro, J.-L.G., and de la Piscina, P.R., J. Catal., 2004, vol. 222, p. 470.

    Article  CAS  Google Scholar 

  2. Llorca, J., Homs, N., de la Piscina, P.R., and Dalmon, J., Appl. Catal., B, 2003, vol. 43, p. 355.

    Article  CAS  Google Scholar 

  3. Batista, M.S., Rudye, K., Santos, S., Assaf, M.E., Assaf, M.J., and Ticianelli, A.E., J. Power Sources, 2004, vol. 134, p. 27.

    Article  CAS  Google Scholar 

  4. Benito, M., Sanz, J.L., Isaabel, R., Padilla, R., Arjona, R., and Daza, L., J. Power Sources, 2007, vol. 169, p. 167.

    Article  CAS  Google Scholar 

  5. Llorca, J., Homs, N., and de la Piscina, P.R., J. Catal., 2004, vol. 227, p. 556.

    Article  CAS  Google Scholar 

  6. Freni, S., Cavallaro, S., Mondello, N., Spadaro, L., and Frusteri, F., Catal. Commun., 2003, vol. 4, p. 259.

    Article  CAS  Google Scholar 

  7. Cavallaro, S., Chiodo, V., Freni, S., Mondello, N., and Frusteri, F., Appl. Catal., A, 2003, vol. 249, p. 119.

    Article  CAS  Google Scholar 

  8. Rasko, J., Hancz, A., and Erdohelyi, A., Appl. Catal., A, 2004, vol. 269, p. 13.

    Article  CAS  Google Scholar 

  9. Bergamaschi, V.S., Carvalho, F.M.S., Rodrigues, C., and Fernandes, D.B., Chem. Eng. J., 2005, vol. 112, p. 153.

    Article  CAS  Google Scholar 

  10. Yang, Y., Ma, J., and Wu, F., Int. J. Hydrogen Energy, 2006, vol. 31, p. 877.

    Article  CAS  Google Scholar 

  11. Cavallaro, S., Mondello, N., and Freni, S., J. Power Sources, 2001, vol. 102, p. 198.

    Article  CAS  Google Scholar 

  12. De Lima, M.S., Cruz, O.I., Jacobs, G., Davis, H.B., Mattos, V.L., and Noronha, B.F., J. Catal., 2008, vol. 257, p. 356.

    Article  Google Scholar 

  13. Cai, W., Wang, F., Zhan, E., Van Veen, A.C., Mirodatos, C., and Shen, W., J. Catal., 2008, vol. 257, p. 96.

    Article  CAS  Google Scholar 

  14. Liguras, D.K., Kondarides, D.I., and Verykios, X.E., Appl. Catal., B, 2003, vol. 43, p. 345.

    Article  CAS  Google Scholar 

  15. Frusteri, F., Freni, S., Spadaro, L., Chiodo, V., Bonura, G., Donato, S., and Cavallaro, S., Catal. Commun., 2004, vol. 5, p. 611.

    Article  CAS  Google Scholar 

  16. Galvita, V.V., Semin, G.L., Belyaev, V.D., Semikolenov, V.A., Tsiarakas, P., and Sobyanin, V.A., Appl. Catal., A, 2001, vol. 220, p. 123.

    Article  CAS  Google Scholar 

  17. Galvita, V.V., Belyaev, V.D., Semikolenov, V.A., Tsiakaras, P., Frumin, A.V., and Sobyanin, V.A., React. Kinet. Catal. Lett., 2002, vol. 76, p. 343.

    Article  CAS  Google Scholar 

  18. Kirillov, V.A., Meshcheryakov, V.D., Sobyanin, V.A., Belyaev, V.D., Amosov, Yu.I., Kuzin, N.A., and Bobrin, A.S., Teor. Osn. Khim. Tekhnol., 2008, vol. 42, no. 1, p. 3 [Theor. Found. Chem. Eng. (Engl. Transl.), vol. 42, no. 1, p. 1].

    Google Scholar 

  19. Badmaev, S.D. and Snytnikov, P.V., Int. J. Hydrogen Energy, 2008, vol. 33, p. 3026.

    Article  CAS  Google Scholar 

  20. Bi, J., Hong, Y., Lee, C., Yeh, C., and Wang, C., Catal. Today, 2007, vol. 129, p. 322.

    Article  CAS  Google Scholar 

  21. Pereira, B.E., Homs, N., Marti, S., Fierro, J., and de la Piscina, P.R., J. Catal., 2008, vol. 257, p. 206.

  22. Churakova, E.M., Badmaev, S.D., Gubanov, A.I., Plyusnin, P.E., Snytnikov, P.V., Korenev, S.V., and Sobyanin, V.A., Tezisy dokladov VI Vseross. konf. po khimii poliyadernykh soedinenii i klasterov (Proc. VI Russian Conf. on the Chemistry of Polynuclear Compounds and Clusters), Kazan, 2009, pp. 136.

  23. JSRDS-ISDD File, 1997.

  24. Galvita, V.V., Belyaev, V.D., Frumin, A.V., Demin, A.K., Tsiakaras, P.E., and Sobyanin, V.A., Solid State Ionics, 2002, vols. 152–153, p. 551.

    Article  Google Scholar 

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Correspondence to E. M. Churakova.

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Original Russian Text © E.M. Churakova, S.D. Badmaev, P.V. Snytnikov, A.I. Gubanov, E.Yu. Filatov, P.E. Plyusnin, V.D. Belyaev, S.V. Korenev, V.A. Sobyanin, 2010, published in Kinetika i Kataliz, 2010, Vol. 51, No. 6, pp. 923–928.

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Churakova, E.M., Badmaev, S.D., Snytnikov, P.V. et al. Bimetallic Rh-Co/ZrO2 catalysts for ethanol steam reforming into hydrogen-containing gas. Kinet Catal 51, 893–897 (2010). https://doi.org/10.1134/S0023158410060157

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