Abstract
The effect of synthesis conditions, the nature of components, and the ratio between the components on the phase composition, the texture, and the redox and catalytic properties of the Ce-Zr-O, Ce-Zr-M1-O (M1 = Mn, Ni, Cu, Y, La, Pr, or Nd), N/Ce-Zr-O (N = Rh, Pd, or Pt), and Pd/Ce-Zr-M2-O/Al2O3 (M2 = Mg, Ca, Sr, Ba, Y, La, Pr, Nd, or Sm) was considered. A cubic solid solution with the fluorite structure was formed on the introduction of <50 mol % zirconium into CeO2, and the stability of this solid solution depended on preparation procedure and treatment conditions. The presence of transition or rare earth elements in certain concentrations extended the range of compositions with the retained fluorite structure. The texture of the Ce-Zr-O system mainly depended on treatment temperature. An increase in this temperature resulted in a decrease in the specific surface area of the samples. The total pore volume varied over the range of 0.2–0.3 cm3/g and depended on the Ce/Zr ratio. The presence of transition or rare earth elements either increased the specific surface area of the system or made it more stable to thermal treatment. The introduction of the isovalent cation Zr4+ into CeO2 increased the number of lattice defects both on the surface and in the bulk to increase the mobility of oxygen and facilitate its diffusion in the Ce1 − x Zr x O2 lattice. The catalytic properties of the Ce-Zr-M1-O or N/Ce-Zr-M2-O systems were due to the presence of anion vacancies and the easy transitions Ce4+ ai Ce3+, M 2n+1 ai M n+1 , and N δ+ → N 0 in the case of noble metals.
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Leonov, A.I., Andreeva, A.B., and Keler, E.K., Khimiya vysokotemperaturnykh materialov (Chemistry of High-Temperature Materials), Leningrad: Nauka, 1967, p. 91.
Trovarelli, A., de Leitenburg, C., Boaro, M., and Dolcetti, G., Catal. Today, 1999, vol. 50, p. 353.
Bernal, S., Kaspar, J., and Trovarelli, A., Catal. Today, 1999, vol. 50, p. 175.
Sohier, M.P., Wrobel, G., Bonnelle, J.P., and Marcq, J.P., Appl. Catal., 1992, vol. 84, p. 169.
Eur. Patent 8508210, 1986.
Harrison, B., Diwell, A.F., and Hallett, C., Platinum Met. Rev., 1988, vol. 32, no. 2, p. 73.
Padeste, C., Cant, N.W., and Trimm, D.L., Catal. Lett., 1993, vol. 18, p. 305.
Sanchez, M.G. and Gazquez, J.L., J. Catal., 1987, vol. 104, p. 120.
Hermann, J.M., Hoang-Van, C., Dibansa, L., and Harivololona, R.J., J. Catal., 1996, vol. 159, p. 361.
De Leitenburg, C., Trovarelli, A., Liorca, J., Cavani, F., and Bini, G., Appl. Catal., A, 1996, vol. 139, p. 161.
Choudhary, T.V., Banerjee, S., and Choudhary, V.R., Appl. Catal., A, 2002, vol. 234, p. 1.
Eigenmann, F., Maciejewski, M., and Baiker, A., Appl. Catal., B, 2006, vol. 62, p. 311.
Diagne, C., Idriss, H., and Kiennemann, A., Catal. Commun., 2002, vol. 3, p. 565.
Courcot, D., Abi-Aad, E., Capelle, S., and Aboukais, A., Stud. Surf. Sci. Catal., 1998, vol. 116, p. 625.
Trovarelli, A., Catal. Rev. Sci. Eng., 1996, vol. 38, p. 439.
Leonov, A.I., Vysokotemperaturnaya khimiya kislorodnykh soedinenii tseriya (High-Temperature Chemistry of Cerium-Oxygen Compounds), Leningrad: Nauka, 1970, p. 4.
Zachariasen, W., Z. Phys. Chem., 1926, vol. 123, p. 134.
Bevan, D.J.M., J. Inorg. Nucl. Chem., 1955, vol. 1, p. 49.
Spravochnik khimika (Chemist’s Handbook), Perel’man, V.I., Ed., Leningrad: Khimiya, 1971, p. 381.
JCPDS File 28-271, Pennsylvania State Univ., 1975.
Voronkov, A.A., Shumyatskaya, N.G., and Pyatenko, Yu.A., Kristallokhimiya mineralov tsirkoniya i ikh iskusstvennye analogi (Crystal Chemistry of Zirconium Minerals and Their Artificial Analogues), Moscow: Nauka, 1978, p. 3.
Glushkova, V.B. and Sazonova, L.V., in Khimiya vysokotemperaturnykh materialov (Chemistry of Macromolecular Materials), Leningrad: Nauka, 1967, p. 83.
Fujimori, A., Phys. Rev., 1983, vol. 28, p. 2281.
Kotani, A., Mizuta, H., Jo, T., and Parlebas, J.C., Solid State Commun., 1985, vol. 53, p. 805.
Wuilloud, E., Delley, B., Schneider, W.D., and Daer, Y., Phys. Rev. Lett., 1984, vol. 53, p. 202.
Koelling, D., Boring, A., and Wood, J., Solid State Commun., 1983, vol. 47, p. 227.
Hill, S. and Catlow, C.R.A., J. Phys. Chem. Solids, 1993, vol. 54, p. 411.
Sayle, T., Parker, S., and Catlow, C.R.A., Surf. Sci., 1994, vol. 316, p. 329.
Conesa, J., Surf. Sci., 1995, vol. 339, p. 337.
Konner, R., Ricken, M., Nolting, J., and Riess, I., J. Solid State Chem., 1989, vol. 78, p. 136.
Faber, J., Seitz, M., and Mueller, M., J. Phys. Chem., 1976, vol. 37, p. 909.
Hermann, J., Ramaroson, E., Tempere, J., and Guilleux, M., Appl. Catal., 1989, vol. 53, p. 117.
Sayle, T., Parker, S., and Catlow, C.R.A., J. Chem. Soc., Chem. Commun., 1992, p. 977.
Trovarelli, A., Boaro, M., Rocchini, E., de Leitenburg, C., and Dolcetti, G., J. Alloys Compd., 2001, vols. 323–324, p. 584.
Perrichon, V., Laachir, A., Abournadasse, S., Touret, O., and Blanchard, G., Appl. Catal., 1995, vol. 129, p. 69.
Terrible, D., Trovarelli, A., Llorca, J., de Leitenburg, C., and Dolcetti, G., J. Catal., 1998, vol. 178, p. 299.
Cho, B.K., J. Catal., 1991, vol. 131, p. 74.
Nunan, J.G., Williamson, W.B., and Robota, H.J., SAF Paper no. 960798, 1998.
Duwez, P. and Odell, F., J. Am. Ceram. Soc., 1952, vol. 35, p. 107.
Yashima, M., Arashi, H., Kakihana, M., and Yoshimura, M., J. Am. Ceram. Soc., 1994, vol. 77, p. 1067.
Tani, E., Yoshimura, M., and Somiya, S., J. Am. Ceram. Soc., 1983, vol. 66, p. 506.
Duran, P., Gonzales, M., Moure, C., Jurdo, J.R., and Pascal, C., J. Mater. Sci., 1990, vol. 25, p. 5001.
Meriani, S., J. Phys., 1986, vol. 47, p. C1–485.
Meriani, S., Mater. Sci. Eng., A, 1989, vol. 109, p. 121.
Meriani, S., Mater. Sci. Eng., 1985, vol. 71, p. 369.
Fornasiero, P., Balducci, G., Di Monte, R., Kaspar, J., Sergo, V., Gubitosa, G., Ferrero, A., and Graziani, M., J. Catal., 1996, vol. 164, p. 173.
Vlaic, G., Di Monte, R., Fornasiero, P., Fonda, E., Kaspar, J., and Graziani, M., J. Catal., 1999, vol. 182, p. 378.
Turko, G.A., Ivanova, A.S., Plyasova, L.M., Litvak, G.S., and Rogov, V.A., Kinet. Katal., 2005, vol. 46, no. 6, p. 932 [Kinet. Catal. (Engl. Transl.), vol. 46, no. 6, p. 884].
Bozo, C., Caillard, F., and Guilhaume, N., Appl. Catal., A, 2001, vol. 220, p. 69.
Zyuzin, D.A., Moroz, E.M., Ivanova, A.S., and Zaikovskii, V.I., Neorg. Mater., 2000, vol. 36, no. 4, p. 447 [Inorg. Mater. (Engl. Transl.), vol. 36, no. 4, p. 359].
Zyuzin, D.A., Moroz, E.M., Ivanova, A.S., Shmakov, A.N., and Kustova, G.N., Kinet. Katal., 2004, vol. 45, no. 5, p. 780 [Kinet. Catal. (Engl. Transl.), vol. 45, no. 5, p. 739].
Kol’ko, V.P., Moroz, E.M., Kriventsov, V.V., and Zyuzin, D.A., Izv. Akad. Nauk, Ser. Fiz., 2007, vol. 71, no. 5, p. 718.
Fornasiero, P., Di Monte, R., Rao, G.R., Kaspar, J., Meriani, S., Trovarelli, A., and Graziani, M., J. Catal., 1995, vol. 151, p. 168.
Hartridge, A. and Bhattacharya, A.K., J. Phys. Chem. Solids, 2002, vol. 63, p. 441.
Rossignol, S., Madier, Y., and Duprez, D., Catal. Today, 1999, vol. 50, p. 261.
Fornasiero, P., Balducci, G., Di Monte, R., Kaspar, J., Sergo, V., Gubitosa, G., Ferrero, A., and Graziani, M., J. Catal., 1995, vol. 164, p. 173.
Balducci, G., Fornasiero, P., Di Monte, R., Kaspar, J., Meriani, S., and Graziani, M., Catal. Lett., 1995, vol. 33, p. 193.
Ivanova, A.S., Moroz, E.M., and Litvak, G.S., Kinet. Katal., 1992, vol. 33, p. 1208.
Mirota, T., Hasegawa, T., Aozasa, S., Matsui, H., and Motoyama, M., J. Alloys Compd., 1993, vol. 193, p. 298.
Yashima, M., Morimoto, K., Nobuo, N., and Yoshimura, M., J. Am. Ceram. Soc., 1993, vol. 76, no. 7, p. 1745.
Yashima, M., Morimoto, K., Ishizawa, N., and Yoshimura, M., J. Am. Ceram. Soc., 1993, vol. 76, no. 11, p. 2865.
Vidal, H., Kaspar, J., Pijolat, M., Colon, G., Bernal, S., Cordon, A., Perrichon, V., and Fally, F., Appl. Catal., B, 2000, vol. 27, p. 49.
Terrible, D., Trovarelli, A., Llorca, J., de Leitenburg, C., and Dolcetti, G., Catal. Today, 1998, vol. 43, p. 79.
Colon, G., Valdivieso, F., Pijolat, M., Baker, R.T., Calvino, J.J., and Bernal, S., Catal. Today, 1999, vol. 50, p. 271.
Di Monte, R. and Kaspar, J., Catal. Today, 2005, vol. 100, p. 27.
Kaspar, J., Fornasiero, P., and Graziani, M., Catal. Today, 1999, vol. 50, p. 285.
Jen, H.-W., Graham, G.W., Chun, W., McCabe, R.W., Cuif, J.-P., Deutsch, S.E., and Touret, O., Catal. Today, 1999, vol. 50, p. 309.
Ozawa, M. and Loong, C.-K., Catal. Today, 1999, vol. 50, p. 329.
Yao, H.C. and Yu, YaoY.F., J. Catal., 1984, vol. 86, p. 254.
Trovarelli, A., Catal. Rev. Sci. Eng., 1996, vol. 38, p. 439.
Rao, G.R., Kaspar, J., Meriani, S., Di Monte, R., and Graziani, M., Catal. Lett., 1994, vol. 24, p. 107.
De Leitenburg, C., Goi, D., Primavera, A., Trovarelli, A., and Dolcetti, G., Appl. Catal., B, 1996, vol. 11, p. L29.
Boaro, M., de Leitenburg, C., Dolcetti, G., and Trovarelli, A., J. Catal., 2000, vol. 193, p. 338.
Madier, Y., Descorme, C., Le Govic, A.M., and Duprez, D., J. Phys. Chem. B, 1999, vol. 103, p. 10999.
Descorme, C., Madier, Y., and Duprez, D., J. Catal., 2000, vol. 196, p. 167.
Li, C., Domen, K., Maruya, K.-I., and Onishi, T., J. Am. Chem. Soc., 1989, vol. 111, p. 7683.
Li, C., Domen, K., Maruya, K.-I., and Onishi, T., J. Catal., 1990, vol. 123, p. 436.
Imamura, S., Shono, M., Okamoto, N., Haneda, A., and Ishida, S., Appl. Catal., A, 1996, vol. 142, p. 279.
Machida, M., Uto, M., Kurogi, D., and Kijima, T., Chem. Mater., 2000, vol. 12, p. 3158.
Qi, G. and Yang, R.T., J. Catal., 2003, vol. 217, p. 434.
Qi, G., Yang, R.T., and Chang, R., Appl. Catal., B, 2004, vol. 51, p. 93.
Qi, G. and Yang, R.T., J. Phys. Chem. B, 2004, vol. 108, no. 40, p. 15738.
Lamonier, C., Ponchel, A., Huysser, A., and Jalowiecki-Duhamel, L., Catal. Today, 1999, vol. 50, p. 247.
Lamonier, C., Bennani, A., Huysser, A., Aboukais, A., and Wrobel, G., J. Chem. Soc., Faraday Trans., 1996, vol. 92, p. 131.
Kacimi, S., Duprez, D., and Dalmon, J.A., J. Chem. Phys., 1997, vol. 94, p. 535.
Takeguchi, T., Furukama, S., and Inoue, M., J. Catal., 2001, vol. 202, p. 14.
Sermon, P.Q. and Bond, G.C., Catal. Rev. Sci. Eng., 1973, vol. 8, p. 211.
Bianchi, D., Gardes, G.E., Pajonk, G.M., and Teichner, S.J., J. Catal., 1975, vol. 38, p. 135.
Kulyova, S.P., Lunina, E.V., Lunin, V.V., Kostyuk, B.G., Muravyova, G.P., Kharlanov, A.N., Zhilinskaya, E.A., and Aboukais, A., Chem. Mater., 2001, vol. 13, p. 1491.
Ikryannikova, L.M., Aksenov, A.A., Markaryan, G.L., Kostyuk, B.G., Kharlanov, A.N., and Lunina, E.V., Appl. Catal., A, 2001, vol. 210, p. 225.
Rohart, E., Larcher, O., Deutsch, S., Hedouin, C., Aimin, H., Fajardie, F., Allain, M., and Macaudiere, P., Top. Catal., 2004, vols. 30/31, p. 417.
Ivanova, A.S., Kinet. Katal., 2001, vol. 42, no. 3, p. 394 [Kinet. Catal. (Engl. Transl.), vol. 42, no. 3, p. 354].
Turko, G.A., Ivanova, A.S., Plyasova, L.M., Litvak, G.S., Rogov, V.A., Slavinskaya, E.M., Polukhina, I.A., and Noskov, A.S., Kinet. Katal., 2007, vol. 48, no. 1, p. 150 [Kinet. Catal. (Engl. Transl.), vol. 48, no. 1, p. 143].
Primavera, A., Trovarelli, A., de Leitenburg, C., Dolcetti, G., and Llorca, J., Stud. Surf. Sci. Catal., 1998, vol. 119, p. 87.
Bozo, C., Guilhaume, N., and Herrmann, J.-M., J. Catal., 2001, vol. 203, p. 393.
Noronha, F.B., Fendley, E.C., Soares, R.R., Alvarez, W.E., and Resasco, D.E., Chem. Eng. J., 2001, vol. 82, p. 21.
Diagne, C., Idriss, H., and Kiennemann, A., Catal. Commun., 2002, vol. 3, p. 565.
Rao, G.R., Fornasiero, P., Monte, R.D., Kaspar, J., Vlaic, G., Balducci, G., Meriani, S., Gubitosa, G., Cremona, A., and Graziani, M., J. Catal., 1996, vol. 162, p. 1.
Nunan, J.G., Robota, H.J., Cohn, M.J., and Bradley, S.A., J. Catal., 1992, vol. 133, p. 309.
Bernal, S., Calvino, J.J., Cifredo, G.A., Rodriguez-Izqueirdo, J.M., Perrichon, V., and Laachir, A., J. Catal., 1992, vol. 137, p. 1.
Ho, C., Yu, J.C., Wang, X., Lai, S., and Qiu, Y., J. Mater. Chem., 2005, vol. 15, p. 2193.
Liu, Y., Hayakawa, T., Ishii, T., Kumagai, M., Yasuda, H., Suzuki, K., Hamakawa, S., and Murata, K., Appl. Catal., A, 2001, vol. 210, p. 301.
Imamura, S., Higashihara, T., Saito, Y., Aritani, H., Kanai, H., Matsumura, Y., and Tsuda, N., Catal. Today, 1999, vol. 50, p. 369.
Fornasiero, P., Kaspar, J., Sergo, V., and Graziani, M., J. Catal., 1999, vol. 182, p. 56.
Hickey, N., Fornasiero, P., Kaspar, J., Gatica, J.M., and Bernal, S., J. Catal., 2001, vol. 200, p. 181.
Lieske, H., Lietz, G., Spindler, H., and Voelter, J., J. Catal., 1983, vol. 182, p. 8.
Busca, G. and Lorenzelli, V., J. Mater. Chem., 1982, vol. 7, p. 89.
Karpinski, Z., Adv. Catal., 1990, vol. 37, p. 45.
Kiennemann, A., Breault, R., and Hindermann, J.P., J. Chem. Soc., Faraday Trans., 1987, vol. 83, p. 2119.
Bernal, S., Blanco, G., Calvino, J.J., Gatica, J.M., Omil, J.A., and Pintado, J.M., Top. Catal., 2004, vol. 28, p. 31.
Xiao, L., Sun, K., Yang, Y., and Xu, X., Catal. Lett., 2004, vol. 95, p. 151.
Yue, B., Zhou, R., Wang, Y., and Zheng, X., J. Mol. Catal. A: Chem., 2005, vol. 238, p. 241.
Yue, B., Zhou, Ra., Wang, Y., and Zheng, X., Appl. Catal., A, 2005, vol. 295, p. 31.
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Original Russian Text © A.S. Ivanova, 2009, published in Kinetika i Kataliz, 2009, Vol. 50, No. 6, pp. 831–849.
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Ivanova, A.S. Physicochemical and catalytic properties of systems based on CeO2 . Kinet Catal 50, 797–815 (2009). https://doi.org/10.1134/S0023158409060020
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DOI: https://doi.org/10.1134/S0023158409060020