Skip to main content
SpringerLink
Log in

Genesis of the active-component precursor in the synthesis of Pt/Al2O3 catalysts: I. Transformation of the [PtCl6]2− complex in the interaction between chloroplatinic acid and the γ-Al2O3 surface

  • Published:
Kinetics and Catalysis Aims and scope Submit manuscript

Abstract

Gradient elution experiments have revealed the difference between platinum complexes in terms of the strength of their interaction with the alumina surface. A considerable part (30–40%) of the supported platinum is nondesorbable via competitive ion exchange reactions or upon changes in the charge state of the support surface. The surface platinum complexes can be divided into ion-exchangeable and coordinatively fixed species according to the nature of their bonding with aluminum oxide. Combining desorption and spectroscopic methods (EXAFS and diffuse reflectance spectroscopy) has made it possible to characterize the surface complexes. The strongest metal-support interaction takes place in the fixation of hydrolyzed platinum species.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Brunelle, J.P., Pure Appl. Chem., 1978, vol. 50, p. 1211.

    Article  CAS  Google Scholar 

  2. Heise, F.J. and Schwarz, J.A., J. Colloid Interface Sci., 1986, vol. 113, p. 55.

    Article  CAS  Google Scholar 

  3. Shah, A. and Regalbuto, J.R., Langmuir, 1994, vol. 10, p. 500.

    Article  CAS  Google Scholar 

  4. Regalbuto, J.R., Navada, A., Shadid, S., Bricker, M.L., and Chen, Q., J. Catal., 1999, vol. 184, p. 335.

    Article  CAS  Google Scholar 

  5. Spieker, W.A. and Regalbuto, J.R., Chem. Eng. Sci., 2000, vol. 56, p. 2365.

    Google Scholar 

  6. Agashe, K. and Regalbuto, J.R., J. Colloid Interface Sci., 1997, vol. 185, p. 174.

    Article  CAS  Google Scholar 

  7. Spieker, W.A., Liu, J., Miller, J.T., Kropf, A.J., and Regalbuto, J.R., Appl. Catal., A, 2002, vol. 232, p. 219.

    Article  CAS  Google Scholar 

  8. Spieker, W.A., Liu, J., Hao, X., Miller, J.T., Kropf, A.J., and Regalbuto, J.R., Appl. Catal., A, 2003, vol. 243, p. 53.

    Article  CAS  Google Scholar 

  9. Mang, T., Breitscheidel, B., Polanek, P., and Knozinger, H., Appl. Catal., A, 1993, vol. 106, p. 239.

    Article  CAS  Google Scholar 

  10. Boitiaux, J.P., Deves, J.M., Didillon, B., and Marcilly, C.R., in Catalytic Naphtha Reforming: Science and Technology, New York: Marcel Dekker, 1995, p. 79.

    Google Scholar 

  11. Shelimov, B., Lambert, J.-F., Che, M., and Didillon, B., J. Am. Chem. Soc., 1999, vol. 121, p. 545.

    Article  CAS  Google Scholar 

  12. Shelimov, B., Lambert, J.-F., and Didillon, B., J. Mol. Catal., 2000, vol. 158, p. 91.

    Article  CAS  Google Scholar 

  13. Santacesaria, E., Carra, S., and Adami, J., Ind. Eng. Chem. Prod. Res. Dev., 1977, vol. 16, no. 1, p. 41.

    Article  CAS  Google Scholar 

  14. Maatman, R.W., Manaffy, P., Hoekstra, P., and Addink, C., J. Catal., 1971, vol. 23, p. 105.

    Article  CAS  Google Scholar 

  15. Tsymbal, T.V., Doronin, V.P., Al’t, L.Ya., and Duplyakin, V.K., V Mezhdunar. Simp. po svyazi mezhdu gomogennym i geterogennym katalizom (V Int. Symp. on the Relation between Homogeneous and Heterogeneous Catalyses), Novosibirsk, 1986, vol. 2, part 2, p. 108.

    CAS  Google Scholar 

  16. Kireeva, T.V., Doronin, V.P., Alt, L.Ya., and Duplyakin, V.K., React. Kinet. Catal. Lett., 1987, vol. 34, no. 2, p. 261.

    Article  CAS  Google Scholar 

  17. Morterra, C. and Magnacca, G., Catal. Today, 1996, vol. 27, p. 497.

    Article  CAS  Google Scholar 

  18. Knozinger, H. and Ratnasamy, P., Catal. Rev. Sci. Eng., 1978, vol. 17, p. 31.

    Article  Google Scholar 

  19. Tsyganenko, A.A. and Mardilovich, P.P., J. Chem. Soc., Faraday Trans., 1996, vol. 92, p. 4843.

    Article  CAS  Google Scholar 

  20. Ginzburg, S.I., Gladyshevskaya, K.A., Ezerskaya, N.A., et al., Rukovodstvo po khimicheskomu analizu platinovykh metallov i zolota (Guide to the Chemical Analysis of the Platinum Metals and Gold), Moscow: Nauka, 1965.

    Google Scholar 

  21. Rieman, W. and Walton, H., Ion Exchange in Analytical Chemistry, Oxford: Pergamon, 1970.

    Google Scholar 

  22. Samuelson, O., Ion Exchange Separations in Analytical Chemistry, New York: Wiley, 1963.

    Google Scholar 

  23. Duplyakin, V.K., Fenelonov, V.B., Rikhter, K., Rodionov, A.V., Seflut, Kh., Kheifets, L.I., Neimark, A.V., and Moskovtsev, V.V., in Nauchnye osnovy tekhnologii katalizatorov (Scientific Foundations of Catalyst Technology), Novosibirsk, 1981, issue 13, p. 137.

  24. Charlot, G., Les méthodes de la chimie analytique, Paris: Masson, 1961.

    Google Scholar 

  25. Cox, L.E., Peters, D.G., and Wehry, E.L., J. Inorg. Nucl. Chem., 1972, vol. 34, p. 297.

    Article  CAS  Google Scholar 

  26. Zolotov, Yu.A., Varshal, G.M., and Ivanov, V.M., Analiticheskaya khimiya metallov platinovoi gruppy (Analytical Chemistry of the Platinum Metals), Moscow: KomKnig, 2005.

    Google Scholar 

  27. Lever, A.B.P., Inorganic Electronic Spectroscopy, Amsterdam: Elsevier, 1984.

    Google Scholar 

  28. Buslaeva, T.M., Umreiko, D.S., Novitskii, G.G., et al., Khimiya i spektroskopiya galogenidov platinovykh metallov (Chemistry and Spectroscopy of Platinum Metal Halides), Minsk: Universitetskoe, 1990.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Hydrocarbon Processing, Siberian Branch, Russian Academy of Sciences, Omsk, 644040, Russia

    O. B. Bel’skaya, R. Kh. Karymova & V. K. Duplyakin

  2. Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Science, Novosibirsk, 630090, Russia

    D. I. Kochubey

Authors
  1. O. B. Bel’skaya
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. R. Kh. Karymova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. D. I. Kochubey
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. V. K. Duplyakin
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to O. B. Bel’skaya.

Additional information

Original Russian Text © O.B. Bel’skaya, R.Kh. Karymova, D.I. Kochubey, V.K. Duplyakin, 2008, published in Kinetika i Kataliz, 2008, Vol. 49, No. 5, pp. 754–763.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Bel’skaya, O.B., Karymova, R.K., Kochubey, D.I. et al. Genesis of the active-component precursor in the synthesis of Pt/Al2O3 catalysts: I. Transformation of the [PtCl6]2− complex in the interaction between chloroplatinic acid and the γ-Al2O3 surface. Kinet Catal 49, 720–728 (2008). https://doi.org/10.1134/S0023158408050170

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0023158408050170

Keywords

Search

Navigation