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STRUCTURALLY CHARACTERIZED SELF-ASSEMBLED HETEROBIMETALLIC Ni(II)–Eu(III)-SALAMO-BIPYRIDINE COORDINATION POLYMER: SYNTHESIS, PHOTOPHYSICAL AND ANTIMICROBIAL PROPERTIES

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Abstract

An independent self-assembling heterobimetallic [Ni(II)–Eu(III)] salamo-like coordination polymer, \(^1_\infty\)[Ni(L)Eu(NO3)3(4,4′-bipy)], is synthesized by the one-pot reaction of a symmetrical salamo-like hexadentate ligand (H2L = 6,6′-dimethoxy-2,2′-[1,2-ethylenedioxybis(nitrilomethylidyne)]diphenol), Ni(OAc)2·4H2O, Eu(NO3)3·6H2O, and 4,4′-bipy. The coordination polymer is obtained by the reaction in the 1:1:1:1 ratio and characterized by elemental analyses, IR and UV-Vis absorption spectra, and single crystal X-ray diffraction. The newly synthesized polymer is constructed from heterobimetallic [Ni(II)(L)Eu(III)] units connected by the 4,4′-bipy exodentate ligand bearing N donor atoms. Meanwhile, the hydrogen bonding, π⋯π stacking and C–H⋯π interactions play an important role in the structure of the coordination polymer. In terms of the antibacterial activity, the polymer dissolved in DMF has a good antibacterial effect on Staphylococcus aureus.

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Funding

This work was supported by the National Natural Science Foundation of China (21761018), Science and Technology Program of Gansu Province (18YF1GA057) and the Program for Excellent Team of Scientific Research in Lanzhou Jiaotong University (201706), three of which are gratefully acknowledged.

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  1. School of Chemistry and Biological Engineering, Lanzhou Jiaotong University, P. R. China

    H R Mu, X X An, C Liu, Y Zhang & W K Dong

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  1. H R Mu
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  2. X X An
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  3. C Liu
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  4. Y Zhang
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Correspondence to W K Dong.

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Mu, H.R., An, X.X., Liu, C. et al. STRUCTURALLY CHARACTERIZED SELF-ASSEMBLED HETEROBIMETALLIC Ni(II)–Eu(III)-SALAMO-BIPYRIDINE COORDINATION POLYMER: SYNTHESIS, PHOTOPHYSICAL AND ANTIMICROBIAL PROPERTIES. J Struct Chem 61, 1155–1166 (2020). https://doi.org/10.1134/S0022476620070203

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