Skip to main content
SpringerLink
Log in

Complexation and Isomerization of [β-Mo8O26]4− in the Presence of Ag+ and DMF

  • Published:
Journal of Structural Chemistry Aims and scope Submit manuscript

Abstract

In the work, we describe the synthesis of five novel complexes based on the octamolybdate anion, the Ag+ cation, and organic ligands: (Bu4N)8[Mo8O26Ag2(DMF)3.6(N2S3C4H6)0.2]2[Mo8O26Ag2(DMF)(N2S3C4H6)]2(1), (Bu4N)4[Mo8O26Ag2(DMF)4][Mo8O26Ag2(DMF)2] (2), (Bu4N)3[Mo8O26Ag2(NO3)(DMF)] (3), (Bu4N)4× ×[α-Mo8O26]·1,4DMF (4), and (Bu4N)4 [α-Mo8O26]·2DMF (5). All compounds are characterized by single crystal X-ray diffraction, IR spectroscopy, and the elemental analysis.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. O. A. Kholdeeva, G. M. Maksimov, R. I. Maksimovskaya et al. Inorg. Chem., 2006, 45, 7224–7234.

    CAS  PubMed  Google Scholar 

  2. P. Jiménez-Lozano, I. Y. Skobelev, O. A. Kholdeeva et al. Inorg. Chem., 2016, 55, 6080–6084.

    PubMed  Google Scholar 

  3. A. R. Parent, T. P. Brewster, W. De Wolf et al. Inorg. Chem., 2012, 51, 6147–6152.

    CAS  PubMed  Google Scholar 

  4. A. Sartorel, M. Bonchio, S. Campagna et al. Chem. Soc. Rev., 2013, 42, 2262–2280.

    CAS  PubMed  Google Scholar 

  5. M. Shiddiq, D. Komijani, Y. Duan et al. Nature, 2016, 531, 348–351.

    CAS  PubMed  Google Scholar 

  6. A. Bijelic and A. Rompel. Coord. Chem. Rev., 2015, 299.

  7. A. Blazevic, E. Al-Sayed, A. Roller et al. Chem. A Eur. J., 2015, 21, 4762–4771.

    CAS  Google Scholar 

  8. T. Buchecker, P. Schmid, I. Grillo et al. J. Am. Chem. Soc., 2019, 141, 6890–6899.

    CAS  PubMed  Google Scholar 

  9. M. Bonchio, Z. Syrgiannis, M. Burian et al. Nat. Chem., 2019, 11, 146–153.

    CAS  PubMed  Google Scholar 

  10. M. Stuckart and K. Y. Monakhov. Chem. Sci., 2019, 10, 4364–4376.

    CAS  PubMed  PubMed Central  Google Scholar 

  11. A. M. Douvas, D. Tsikritzis, C. Tselios et al. Phys. Chem. Chem. Phys., 2019, 21, 427–437.

    CAS  Google Scholar 

  12. C. Li, N. Mizuno, K. Yamaguchi et al. J. Am. Chem. Soc., 2019, 141, 7687–7692.

    CAS  PubMed  Google Scholar 

  13. S. Martín, Y. Takashima, C.-G. Lin et al. Inorg. Chem., 2019, 58, 4110–4116.

    PubMed  Google Scholar 

  14. A. A. Shmakova, V. V. Volchek, P. A. Abramov, and M. N. Sokolov. J. Struct. Chem., 2018, 59, 1427–1432.

    CAS  Google Scholar 

  15. A. A. Mukhacheva, P. A. Abramov, and M. N. Sokolov. J. Struct. Chem., 2019, 60(4), 647–653.

    CAS  Google Scholar 

  16. Y. Wu, R. Shi, Y.-L. Wu et al. J. Am. Chem. Soc., 2015, 137, 4111–4118.

    CAS  PubMed  Google Scholar 

  17. M. A. Moussawi, N. Leclerc-Laronze, S. Floquet et al. J. Am. Chem. Soc., 2017, 139, 12793–12803.

    CAS  PubMed  Google Scholar 

  18. C. Falaise, M. A. Moussawi, S. Floquet et al. J. Am. Chem. Soc., 2018, 140, 11198–11201.

    CAS  PubMed  Google Scholar 

  19. Polyoxometalate chemistry Vol. 69 / Eds. R. van Eldik and L. Cronin. Academic Press, 2017.

  20. G. Guillemot, E. Matricardi, L.-M. Chamoreau et al. ACS Catal., 2015, 5, 7415–7423.

    CAS  Google Scholar 

  21. G. Izzet, B. Abécassis, D. Brouri et al. J. Am. Chem. Soc., 2016, 138, 5093–5099.

    CAS  PubMed  Google Scholar 

  22. S. A. Adonin, E. V. Peresypkina, M. N. Sokolov et al. Inorg. Chem., 2014, 53, 6886–6892.

    CAS  PubMed  Google Scholar 

  23. B. Dong and Q. Xu. Inorg. Chem., 2009, 48, 5861–5873.

    CAS  PubMed  Google Scholar 

  24. S. G. Kozlova, S. A. Adonin, M. N. Sokolov et al. Inorg. Chim. Acta, 2016, 443, 1–6.

    CAS  Google Scholar 

  25. A. V. Artem’ev, J. A. Eremina, E. V. Lider et al. Polyhedron, 2017, 138, 218–224.

    Google Scholar 

  26. M. I. Rogovoy, D. G. Samsonenko, M. I. Rakhmanova et al. Inorg. Chim. Acta, 2019, 489, 19–26.

    CAS  Google Scholar 

  27. A. V. Artem’ev, I. Y. Bagryanskaya, E. P. Doronina et al. Dalton Trans., 2017, 46, 12425–12429.

    PubMed  Google Scholar 

  28. M. Z. Shafikov, R. Czerwieniec, and H. Yersin. Dalton Trans., 2019, 48, 2802–2806.

    CAS  PubMed  Google Scholar 

  29. K. Nilsson, Å. Oskarsson, J. Songstad et al. Acta Chem. Scand., 1984, 38a, 79–85.

    Google Scholar 

  30. C.-C. Dörtbudak, K. Lux, and A. Kornath. Z. Naturforsch. B, 2014, 69, 373–375.

    Google Scholar 

  31. D. V. Peryshkov and S. H. Strauss. Inorg. Chem., 2017, 56, 4072–4083.

    CAS  PubMed  Google Scholar 

  32. D.-B. Dang, H. Gao, Y. Bai et al. Inorg. Chem. Commun., 2010, 13, 37–41.

    CAS  Google Scholar 

  33. T. McGlone, J. Thiel, C. Streb et al. Chem. Commun., 2012, 48, 359–361.

    CAS  Google Scholar 

  34. J. T. Rhule, W. A. Neiwert, K. I. Hardcastle et al. J. Am. Chem. Soc., 2001, 123, 12101–12102.

    CAS  PubMed  Google Scholar 

  35. T. McGlone, C. Streb, D. L. Long et al. Adv. Mater., 2010, 22, 4275–4279.

    CAS  PubMed  Google Scholar 

  36. C. Streb, C. Ritchie, D.-L. Long et al. Angew. Chem., Int. Ed., 2007, 46, 7579–7582.

    CAS  Google Scholar 

  37. Inorganic syntheses. Vol. 27. Ed. A. P. Ginsberg. Wiley, 1990.

  38. G. M. Sheldrick. Acta Crystallogr. Sect. A: Found. Adv., 2015, 71, 3–8.

    Google Scholar 

  39. G. M. Sheldrick. Acta Crystallogr. Sect. C: Struct. Chem., 2015, 71, 3–8.

    Google Scholar 

  40. C. B. Hübschle, G. M. Sheldrick, and B. Dittrich. J. Appl. Crystallogr., 2011, 44, 1281–1284.

    PubMed  PubMed Central  Google Scholar 

  41. H. Abbas, A. L. Pickering, D.-L. Long et al. Chem. A Eur. J., 2005, 11, 1071–1078.

    CAS  Google Scholar 

  42. J. Fuchs and H. Hartl. Angew. Chem., Int. Ed. Engl., 1976, 15, 375–376.

    Google Scholar 

  43. S. S. Talismanov, G. G. Aleksandrov, A. Muller et al. Russ. J. Inorg. Chem., 2002, 47, 1320–1329.

    Google Scholar 

  44. L.-X. Cai, S.-C. Li, D.-N. Yan et al. J. Am. Chem. Soc., 2018, 140, 4869–4876.

    CAS  PubMed  Google Scholar 

Download references

Funding

The work was supported by RFBR grant No. 18-33-20067.

Author information

Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    A. V. Chupina, A. A. Mukhacheva, P. A. Abramov & M. N. Sokolov

  2. Novosibirsk State University, Novosibirsk, Russia

    A. V. Chupina, A. A. Mukhacheva, P. A. Abramov & M. N. Sokolov

Authors
  1. A. V. Chupina
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. A. Mukhacheva
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. P. A. Abramov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. M. N. Sokolov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to A. A. Mukhacheva.

Additional information

Conflict of Interests

The authors declare that they have no conflict of interests.

Russian Text © The Author(s), 2020, published in Zhurnal Strukturnoi Khimii, 2020, Vol. 61, No. 2, pp. 315–324.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Chupina, A.V., Mukhacheva, A.A., Abramov, P.A. et al. Complexation and Isomerization of [β-Mo8O26]4− in the Presence of Ag+ and DMF. J Struct Chem 61, 299–308 (2020). https://doi.org/10.1134/S0022476620020158

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0022476620020158

Keywords

Search

Navigation