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An X-ray Spectral Study of the Electronic Structure of Non-Innocent Mono- and Binuclear Platinum Complexes with N-Phenyl-o-Benzosemiquinonediimine

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Abstract

The electronic structure of mono- and binuclear platinum complexes with N-phenyl-o benzosemiquinondiimine ligands was studied using X-ray photoelectron spectroscopy, X-ray absorption spectroscopy, and the density functional theory. The oxidation state of the central platinum ion corresponds to that of Pt(II). Upon the transition from the trans-complex 1 to the cis-complex 2 and to the binuclear complex 3, the electron density on platinum and nitrogen atoms decreases thus testifying the participation of platinum and nitrogen atoms in the oxidation processes and in the formation of binuclear complex 3.

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Acknowledgments

The authors thank Helmholtz-Zentrum Berlin for Materials and Energy for the possibility of recording NEXAFS spectra with the Russian-German Laboratory, and D.A. Smirnov, Coordinator of the Russian-German Laboratory, for his help with the NEXAFS experiment.

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Correspondence to A. D. Fedorenko.

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Russian Text © The Author(s), 2019, published in Zhurnal Strukturnoi Khimii, 2019, Vol. 60, No. 6, pp. 948–958.

Funding

The study was financially supported by the Russian Foundation for Basic Research (project No. 16-03-00047) and the Russian Science Foundation (project No. 14-23-00176). Part of the work was performed within the Government Contract of the Institute of General and Inorganic Chemistry of RAS in the field of basic research.

Conflict of Interests

The authors declare that they have no conflict of interests.

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Ivanova, T.M., Sidorov, A.A., Mazalov, L.N. et al. An X-ray Spectral Study of the Electronic Structure of Non-Innocent Mono- and Binuclear Platinum Complexes with N-Phenyl-o-Benzosemiquinonediimine. J Struct Chem 60, 909–918 (2019). https://doi.org/10.1134/S0022476619060052

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  • DOI: https://doi.org/10.1134/S0022476619060052

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