Abstract
The electronic structure of hexanuclear Mn(II,III) pivalate complexes with tetrahydrofuran and isonicotinamide are studied by X-ray photoelectron spectroscopy and X-ray emission spectroscopy. It is shown that when isonicotinamide substitutes for tetrahydrofuran the spin state of manganese ions is retained; the electron density increases on the manganese and oxygen atoms of the [Mn6(O)2Piv10] core.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
R. Sessoli, D. Gatteschi, A. Caneschi, and M. A. Novak, Nature, 365, 141–143 (1993).
R. Sessoli, H. L. Tsai, A. R. Schake, S. Wang, J. B. Vincent, K. Folting, D. Gatteschi, G. Christou, and D. N. Hendrickson, J. Am. Chem. Soc., 115, 1804–1816 (1993).
T. C. Stamatatos, D. Foguet-Albiol, S. P. Perlepes, C. P. Raptopoulou, A. Terzis, C. S. Patrickios, G. Christou, and A. J. Tasiopoulos, Polyhedron, 25, 1737–1746 (2006).
D. Gatteschi and R. Sessoli, Angew. Chem. Int. Ed., 42, 268–297 (2003).
M. Murugesu, J. Raftery, W. Wernsdorfer, G. Christou, and E. K. Brechin, Inorg. Chem., 43, 4203–4209 (2004).
E. Yu. Fursova and V. I. Ovcharenko, Ross. Khim. Zh., LIII, No. 1, 23–32 (2009).
V. Ovcharenko, E. Fursova, G. Romanenko, and V. Ikorskii, Inorg. Chem., 43, 3332–3334 (2004).
E. Fursova, V. Ovcharenko, K. Nosova, G. Romanenko, and V. Ikorskii, Polyhedron, 24, 2084–2093 (2005).
V. R. Galakhov, B. A. Gizhevskii, L. V. Elokhina, N. N. Loshkareva, S. V. Naumov, M. Raekers, M. Neumann, and A. M. Balbashov, JETP Letters, 91, No. 3, 140–144 (2010).
T. M. Ivanova, A. V. Shchukarev, A. V. Naumkin, A. A. Sidorov, M. A. Kiskin, V. M. Novotvortsev, and I. L. Eremenko, Russ. J. Inorg. Chem., 53, No. 12, 2061–2066 (2008).
A. G. Kochur, T. M. Ivanova, A. V. Shchukarev, A. A. Sidorov, M. A. Kiskin, V. M. Novotvortsev, and I. L. Eremenko, Bull. Russ. Acad. Sci.: Phys., 74, No. 5, 662–667 (2010).
E. Yu. Fursova, V. I. Ovcharenko, A. S. Bogomyakov, and G. V. Romanenko, J. Struct. Chem., 54, No. 1, 164–167 (2013).
D. A. Shyrley, Phys. Rev. B, 5, 4709–4714 (1972).
V. D. Yumatov, A. V. Okotrub, L. N. Mazalov, G. S. Belikova, and T. M. Okhrimenko, J. Struct. Chem., 26, No. 4, 540–545 (1985).
J. S. Stevens, S. J. Byard, C. C. Seaton, G. Sadiq, R. J. Davey, and S. L. M. Schroeder, Phys. Chem. Chem. Phys., 16, 1150–1160 (2014).
G. K. Wertheim, S. Hufner, and H. J. Guggenheim, Phys. Rev. B, 7, 556–558 (1973).
F. de Groot and A. Kotani, Core Level Spectroscopy of Solids, CRC Press (2008).
M. Oku, H. Matsuta, K. Wagatsuma, and T. Konishi, J. Chem. Soc., Faraday Trans., 92, No. 15, 2759–2764 (1996).
C. J. Pollock, M. U. Delgado-Jaime, M. Atanasov, F. Neese, and S. DeBeer, J. Am. Chem. Soc., 136, 9453–9463 (2014).
P. Glatzel and U. Bergmann, Coord. Chem. Rev., 249, 65–95 (2005).
G. Peng, F. M. F. de Groot, K. Hämäläinen, J. A. Moore, X. Wang, M. M. Grush, J. B. Hastings, D. P. Siddons, W. H. Armstrong, O. C. Mullins, and S. P. Cramer, J. Am. Chem. Soc., 116, 2914–2920 (1994).
T. P. Surkova, V. R. Galakhov, and E. Z. Kurmaev, Low Temp. Phys., 35, 79–82 (2009).
Author information
Authors and Affiliations
Corresponding author
Additional information
Translated from Zhurnal Strukturnoi Khimii, Vol. 58, No. 6, pp. 1214–1220, July–August, 2017.
Rights and permissions
About this article
Cite this article
Fedorenko, A.D., Mazalov, L.N., Fursova, E.Y. et al. X-ray photoelectron and X-ray emission study of the electronic structure of hexanuclear Mn(II,III) pivalate complexes. J Struct Chem 58, 1166–1172 (2017). https://doi.org/10.1134/S0022476617060142
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0022476617060142