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Structural and mass spectrometric characterisation of the dinuclear platinum(II) selenido-phenylselenolato complex [Pt2(μ-Se)(μ-SePh)(PPh3)4]PF6

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Abstract

The reaction of [Pt2(μ-Se)2(PPh3)4] with diphenyliodonium bromide gave [Pt2(μ-Se)(μ-SePh)(PPh3)4]+ through arylation of a selenide ligand. The complex is characterised by 31P NMR spectroscopy, elemental microanalysis, ESI mass spectrometry, and a single crystal X-ray diffraction study, which showed the fourmembered {Pt2Se2} ring to be slightly puckered.

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Authors and Affiliations

  1. Department of Chemistry, University of Waikato, Hamilton, New Zealand

    R. G. Fortney-Zirker, W. Henderson & B. K. Nicholson

Authors
  1. R. G. Fortney-Zirker
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  2. W. Henderson
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  3. B. K. Nicholson
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Correspondence to R. G. Fortney-Zirker.

Additional information

The text was submitted by the authors in English. Zhurnal Strukturnoi Khimii, Vol. 56, No. 4, pp. 780-785, July-August, 2015. Original article submitted November 27, 2013.

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Fortney-Zirker, R.G., Henderson, W. & Nicholson, B.K. Structural and mass spectrometric characterisation of the dinuclear platinum(II) selenido-phenylselenolato complex [Pt2(μ-Se)(μ-SePh)(PPh3)4]PF6 . J Struct Chem 56, 730–736 (2015). https://doi.org/10.1134/S0022476615040174

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