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EFfect of alumina modification on the structure of cobalt-containing Fischer-Tropsch synthesis catalysts according to internal-field 59Co NMR data

  • Current NMR and EPR Spectroscopy Methods in Structural Chemistry of Complex Crystals, Glasses, Composites, and Biological Membranes
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Abstract

An internal-field 59Co NMR study of cobalt-containing Fischer-Tropsch synthesis catalysts supported on different alumina modifications was reported. The Co/δ-Al2O3 sample was shown to contain single-domain fcc packing and stacking faults, whereas Co/γ-Al2O3 gave signals from the fcc domain walls, hcp and stacking faults, thus indicating differences in the particle size of the studied samples. T 2 relaxation times were measured; their distribution in a spectrum is non-uniform, which allows signals to be distinguished by their relaxation times. Quantitative measurements of the relative atoms content in different packings revealed that the catalysts have mostly a defect structure. A brief historical background was presented to characterize the internal-field 59Co NMR technique, the related problems, and different approaches to acquired data interpretation.

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References

  1. S. Wurmehl, J. T. Kohlhepp, H. J. M. Swagten, and B. Koopmans, J. Phys. D: Appl. Phys., 41, 1 (2008).

    Article  Google Scholar 

  2. S. Wurmehl, G. H. Fecher, K. Kroth, F. Kronast, H. A. Dürr, Y. Takeda, Y. Saitoh, K. Kobayashi, H.-J. Lin, G. Schönhense, and C. Felser,, J. Phys. D: Appl. Phys., 39, No. 5, 803 (2006).

    Article  CAS  Google Scholar 

  3. C. Meny, E. Jedryka, and P. Panissod, J. Phys.: Condens. Matter., 5, No. 10, 1547 (1993).

    Article  CAS  Google Scholar 

  4. R. C. La Force and G. F. Day, Phys. Rev. Lett., 6, No. 5, 226 (1961).

    Article  Google Scholar 

  5. H. Yasuoka, S. Hoshinouchi, Y. Nakamura, M. Matsui, and K. Adachi, Phys. Status Solidi B, 46, No. 2, K81 (1971).

    Article  CAS  Google Scholar 

  6. J. Durand and M. F. Lapierre, J. Phys. F: Metall. Phys., 6, No. 6, 1185 (1976).

    Article  CAS  Google Scholar 

  7. P. Panissod and C. Mény, Appl. Magn. Res., 19, Nos. 3/4, 447 (2000).

    Article  CAS  Google Scholar 

  8. P. Panissod, J. P. Jay, C. Meny, M. V., E. Jedrica, Hyperfine Interact., 97/98, 75 (1996).

    Article  CAS  Google Scholar 

  9. P. Panissod, in: Structural and Magnetic Investigations of Ferromagnets by NMR. Application to Magnetic Metallic Multilayers, in: Frontiers in Magnetism of Reduced Dimension Systems, V. G. Bar’yakhtar, P. E. Wigen, and N. A. Lesnik (eds.), Kluwer Academic (1998).

  10. G. J. Strijkers, J. T. Kohlhepp, H. J. M. Swagten, and W. J. M. Jonge, Appl. Magn. Res., 19, Nos. 3/4, 461 (2000).

    Article  CAS  Google Scholar 

  11. T. Thomson, P. C. Riedi, Q. Wang, and H. Zabe, J. Appl. Phys., 79, No. 8, 6300 (1996).

    Article  CAS  Google Scholar 

  12. E. Jedryka, M. Wojcik, S. Nadolski, D. Kubinski, M. Parsons, and H. Holloway, J. Appl. Phys., 91, No. 10, 7191 (2002).

    Article  CAS  Google Scholar 

  13. M. Wojcik, C. Christides, E. Jedryka, S. Nadolski, and I. Panagiotopoulos, Phys. Rev. B, 63, No. 1, 012102 (2001).

    Article  Google Scholar 

  14. T. Thomson, P. C. Riedi, and D. Greig, Phys. Rev. B, 50, No. 14, 10319 (1994).

    Article  CAS  Google Scholar 

  15. A. A. Sidorenko, C. Pernechele, P. Lupo, M. Ghidini, M. Solzi, R. De Renzi, I. Bergenti, P. Graziosi, V. Dediu, L. Hueso, and A. T. Hindmarch, Appl. Phys. Lett., 97, No. 16, 162503 (2010).

    Article  Google Scholar 

  16. Y. D. Zhang, J. I. Budnick, W. A. Hines, S. A. Majetich, and E. M. Kirkpatrick, Appl. Phys. Lett., 76, No. 1, 94 (2000).

    Article  CAS  Google Scholar 

  17. M. Shiraishi, H. Kusai, R. Nouchi, T. Nozaki, T. Shinjo, Y. Suzuki, M. Yoshida, and M. Takigawa, Appl. Phys. Lett., 93, No. 5, 53103 (2008).

    Article  Google Scholar 

  18. Y. D. Zhang, W. A. Hines, J. I. Budnick, Z. Zhang, and W. M. H. Sachtler, J. Appl. Phys., 76, No. 10, 6576 (1994).

    Article  CAS  Google Scholar 

  19. T. Thomson, P. C. Riedi, S. Sankar, and A. E. Berkowitz, J. Appl. Phys., 81, No. 8, 5549 (1997).

    Article  CAS  Google Scholar 

  20. E. Jedryka, M. Wojcik, S. Nadolski, H. Pattyn, J. Verheyden, J. Dekoster, and A. Vantomme, J. Appl. Phys., 95, No. 5, 2770 (2004).

    Article  CAS  Google Scholar 

  21. W. Hines, J. Budnick, D. Perry, S. Majetich, R. Booth, and M. Sachan, Phys. Status Solidi B, 248, No. 3, 741 (2011).

    Article  CAS  Google Scholar 

  22. A. Y. Khodakov, W. Chu, and P. Fongarland, Chem. Rev., 107, No. 5, 1692 (2007).

    Article  CAS  Google Scholar 

  23. N. E. Tsakoumis, M. Røning, Ø. Borg, E. Rytter, and A. Holmen,, Catal. Today, 154, Nos. 3/4, 162 (2010).

    Article  CAS  Google Scholar 

  24. M. Sadeqzadeh, H. Karaca, O. V. Safonova, P. Fongarland, S. Chambrey, P. Roussel, A. Griboval-Constant, M. Lacroix, D. Curulla-Ferré, F. Luck, and A. Y. Khodakov, Catal. Today, 164, No. 1, 62 (2011).

    Article  CAS  Google Scholar 

  25. A. N. Murty, M. Seamster, A. N. Thorpe, R. T. Obermyer, and V. U. S. Rao, J. Appl. Phys., 67, No. 9, 5847 (1990).

    Article  CAS  Google Scholar 

  26. A. N. Murty, A. A. Williams, R. T. Obermyer, and V. U. S. Rao, J. Appl. Phys., 61, No. 8, 4361 (1987).

    Article  CAS  Google Scholar 

  27. A. Andreev, A. Salanov, S. Tikhov, S. Cherepanova, V. Zaikovskii, V. Usoltsev, V. Sadykov, and O. Lapina, J. Mater. Sci. Eng. A, 2, No. 2, 121 (2012).

    CAS  Google Scholar 

  28. A. S. Andreev, S. F. Tikhov, A. N. Salanov, S. V. Cherepanova, O. B. Lapina, V. A. Bolotov, Y. Y. Tanashev, J.-B. d’Espinose de Lacaillerie, and V. A. Sadykov, Adv. Mat. Res., 702, 79 (2013).

    Article  Google Scholar 

  29. B. Ernst, S. Libs, P. Chaumette, and A. Kiennemann, Appl. Catal. A: General, 186, Nos. 1/2, 145 (1999).

    Article  CAS  Google Scholar 

  30. W.-J. Wang and Y.-W Chen, Appl. Catal., 77, No. 2, 223 (1991).

    Article  CAS  Google Scholar 

  31. J. Li, G. Jacobs, Y. Zhang, T. Das, B. H. Davis, and R. C. La Force, Appl. Catal. A: General, 223, 195 (2002).

    Article  CAS  Google Scholar 

  32. R. Reuel, J. Catal., 85, No. 1, 78 (1984).

    Article  CAS  Google Scholar 

  33. I. I. Simentsova, A. A. Khassin, G. A. Filonenko, G. K. Chermashentseva, O. A. Bulavchenko, S. V. Cherepanova, and T. M. Yurieva, Russ. Chem. Bull., 63, No. 9, 1796 (2011).

    Google Scholar 

  34. V. I. Chizhik, Quantum Radiophysics. St. Petersburg Publ., St. Petersburg (2004).

    Google Scholar 

  35. A. M. Portis and A. C. Gossard, J. Appl. Phys., 31, No. 5, S205 (1960).

    Article  Google Scholar 

  36. M. Malinowska, M. Wojcik, S. Nadolski, E. Jedryka, C. Meny, P. Panissod, M. Knobel, A. D. C. Viegas, and J. E. Schmidt, J. Magn. Magn. Mater., 198/199, 599 (1999).

    Article  Google Scholar 

  37. J. Sort, S. Surinach, J. S. Munoz, M. D. Baro, M. Wojcik, E. Jedrica, S. Nadolski, N. Sheludko, and J. Nogues, Phys. Rev. B, 68, 14421 (2003).

    Article  Google Scholar 

  38. R. Speight, A. Wong, P. Ellis, P. T. Bishop, T. I. Hyde, T. J. Bastow, and M. E. Smith, Phys. Rev. B, 79, No. 5, 054102 (2009).

    Article  Google Scholar 

  39. A. C. Gossard and A. M. Portis, Phys. Rev. Lett., 3, No. 4, 164 (1959).

    Article  CAS  Google Scholar 

  40. Y. Koi, A. Tsujimura, and T. Kushida, J. Phys. Soc. Jpn., 15, 2100 (1960).

    Article  CAS  Google Scholar 

  41. W. A. Hardy, J. Appl. Phys., 32, No. 3, S122 (1961).

    Article  Google Scholar 

  42. L. E. Toth and S. F. Ravitz, J. Phys. Chem. Solids, 24, No. 1, 1203 (1963).

    Article  CAS  Google Scholar 

  43. L. E. Toth, G. F. Day, R. C. La Force, and S. F. Ravitz, Acta Metall., 12, 311 (1964).

    Article  CAS  Google Scholar 

  44. J. L. Bubendorff, E. Beaurepaire, C. Mény, P. Panissod, and J. P. Bucher, Phys. Rev. B, 56, No. 12, R7120 (1997).

    Article  CAS  Google Scholar 

  45. S. Colis, A. Dinia, C. Mény, P. Panissod, C. Ulhaq-Bouillet, and G. Schmerber, Phys. Rev. B. 62, No. 17, 11709 (2000).

    Article  CAS  Google Scholar 

  46. E. Jedryka, M. Wojcik, S. Nadolski, D. J. Kubinski, H. Holloway, and P. Panissod, J. Appl. Phys., 81, No. 8, 4776 (1997).

    Article  CAS  Google Scholar 

  47. M. Malinowska, C. Meny, E. Jedryka, and P. Panissod, J. Phys.: Condens. Matter., 10, No. 22, 4919 (1998).

    Article  CAS  Google Scholar 

  48. P. Panissod, M. Malinowska, E. Jedrica, M. Wojcik, S. Nadolski, M. Knobel, and J. E. Schmidt, Phys. Rev. B, 63, No. 1, 14408 (2000).

    Article  Google Scholar 

  49. R. Speight, A. Wong, P. Ellis, T. Hyde, P. T. Bishop, and M. E. Smith, Solid State Nucl. Magn. Res., 35, No. 2, 67 (2009).

    Article  CAS  Google Scholar 

  50. M. Cerisier, K. Attenborough, E. Jedryka, M. Wojcik, S. Nadolski, C. Van Haesendonck, and J. P. Celis, J. Appl. Phys., 89, No. 11, 7083 (2001).

    Article  CAS  Google Scholar 

  51. C. Christides, S. Stavroyiannis, D. Niarchos, M. Wojcik, S. Nadolski, and E. Jedryka, Phys. Rev. B. 59, No. 13, 8812 (1999).

    Article  CAS  Google Scholar 

  52. E. Jedryka, W. E. Bailey, M. Wojcik, S. Nadolski, and S. X. Wang, J. Appl. Phys., 85, No. 8, 4439 (1999).

    Article  CAS  Google Scholar 

  53. E. Jedryka, M. Wojcik, S. Nadolski, D. J. Kubinski, and H. Holloway, J. Magn. Magn. Mater., 165, Nos. 1–3, 292 (1997).

    Article  CAS  Google Scholar 

  54. E. Jedryka, M. Wojcik, S. Nadolski, D. J. Kubinski, and H. Holloway, J. Magn. Magn. Mater., 177, 1183 (1998).

    Article  Google Scholar 

  55. E. Jedryka, M. Wojcik, S. Nadolski, T. Stobiecki, and M. Czapkiewicz, J. Magn. Magn. Mater., 156, Nos. 1–3, 38 (1996).

    Article  CAS  Google Scholar 

  56. M. Wojcik, E. Jedryka, S. Nadolski, D. Kubinski, M. Parsons, and H. Holloway, Acta Phys. Pol., A, 97, No. 3, 551 (2000).

    CAS  Google Scholar 

  57. M. Wojcik, E. Jedryka, S. Nadolski, T. Stobiecki, and M. Czapkiewicz, J. Magn. Magn. Mater., 157, 220 (1996).

    Article  Google Scholar 

  58. C. Meny, P. Panissod, P. Humbert, J. P. Nozieres, V. S. Speriosu, B. A. Gurney, and R. Zehringer, J. Magn. Magn. Mater., 121, Nos. 1–3, 406 (1993).

    Article  CAS  Google Scholar 

  59. A. C. Gossard, A. M. Portis, M. Rubinstein, and R. H. Lindquist, Phys. Rev., 138, No. 5A, A1415 (1965).

    Article  Google Scholar 

  60. H. Yasuoka and R. T. Lewis, Phys. Rev., 183, No. 2, 559 (1969).

    Article  CAS  Google Scholar 

  61. M. Kawakami, T. Hihara, and Y. Koi, J. Phys. Soc. Jpn., 33, No. 6, 1591 (1972).

    Article  CAS  Google Scholar 

  62. R. F. Jackson, R. G. Scurlock, D. B. Utton, and T. H. Wilmshurst, in: Proc. Intern. Conf. Magnetism, Nottingham (1964), p. 384.

    Google Scholar 

  63. R. E. Walstedt, J. H. Wernick, and V. Jaccarino, Phys. Rev., 162, No. 2, 301 (1967).

    Article  CAS  Google Scholar 

  64. E. A. Turov, A. P. Tankeev, and M. I. Kurkin, Physics of Metals and Metallography, 28, No. 3, 385 (1969).

    Google Scholar 

  65. E. A. Turov, A. P. Tankeev, and M. I. Kurkin, Physics of Metals and Metallography, 29, No. 4, 747 (1970).

    CAS  Google Scholar 

  66. M. Kawakami and H. Enokiya, J. Phys. Soc. Jpn., 55, No. 11, 4038 (1986).

    Article  CAS  Google Scholar 

  67. S. G. Bailey, D. C. Creagh, and G. V. H. Wilson, Phys. Lett. A, 44, No. 3, 229 (1973).

    Article  CAS  Google Scholar 

  68. H. Enokiya, J. Phys. Soc. Jpn., 42, No. 3, 796.

  69. D. Fekete, H. Boasson, A. Grayevski, V. Zevin, and N. Kaplan, Phys. Rev. B, 17, No. 1, 347 (1978).

    Article  CAS  Google Scholar 

  70. H. P. Kunkel and C. W. Searle, Phys. Rev. B, 23, No. 1, 65 (1981).

    Article  CAS  Google Scholar 

  71. H. Brömer and H. L. Huber, J. Magn. Magn. Mater., 8, No. 1, 61 (1978).

    Article  Google Scholar 

  72. R. Street, D. S. Rodbell, and W. L. Roth, Phys. Rev., 121, No. 1, 84 (1961).

    Article  CAS  Google Scholar 

  73. D. C. Creagh, S. G. Bailey, and G. V. H. Wilson, Philos. Mag., 32, No. 2, 405 (1975).

    Article  CAS  Google Scholar 

  74. P. A. Chernavsky, Russ. Chem. J., XLVI, No. 3, 19.

  75. D. L. Leslie-Pelecky and R. D. Rieke, Chem. Mater., 8, No. 8, 1770 (1996).

    Article  CAS  Google Scholar 

  76. V. S. Pokatilov, Russ. J. Solid State Physics, 48, No. 8, 1436 (2006).

    Google Scholar 

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Correspondence to A. S. Andreev.

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Original Russian Text Copyright © 2013 by A. S. Andreev, O. B. Lapina, J.-B. d’Espinose de Lacaillerie, A. A. Khassin

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Translated from Zhurnal Strukturnoi Khimii, Vol. 54, Supplement 1, pp. S104–S112, 2013.

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Andreev, A.S., Lapina, O.B., d’Espinose de Lacaillerie, J.B. et al. EFfect of alumina modification on the structure of cobalt-containing Fischer-Tropsch synthesis catalysts according to internal-field 59Co NMR data. J Struct Chem 54 (Suppl 1), 102–110 (2013). https://doi.org/10.1134/S0022476613070093

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