Abstract
An internal-field 59Co NMR study of cobalt-containing Fischer-Tropsch synthesis catalysts supported on different alumina modifications was reported. The Co/δ-Al2O3 sample was shown to contain single-domain fcc packing and stacking faults, whereas Co/γ-Al2O3 gave signals from the fcc domain walls, hcp and stacking faults, thus indicating differences in the particle size of the studied samples. T 2 relaxation times were measured; their distribution in a spectrum is non-uniform, which allows signals to be distinguished by their relaxation times. Quantitative measurements of the relative atoms content in different packings revealed that the catalysts have mostly a defect structure. A brief historical background was presented to characterize the internal-field 59Co NMR technique, the related problems, and different approaches to acquired data interpretation.
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Original Russian Text Copyright © 2013 by A. S. Andreev, O. B. Lapina, J.-B. d’Espinose de Lacaillerie, A. A. Khassin
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Translated from Zhurnal Strukturnoi Khimii, Vol. 54, Supplement 1, pp. S104–S112, 2013.
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Andreev, A.S., Lapina, O.B., d’Espinose de Lacaillerie, J.B. et al. EFfect of alumina modification on the structure of cobalt-containing Fischer-Tropsch synthesis catalysts according to internal-field 59Co NMR data. J Struct Chem 54 (Suppl 1), 102–110 (2013). https://doi.org/10.1134/S0022476613070093
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DOI: https://doi.org/10.1134/S0022476613070093