Abstract
Works devoted to developing the methods of producing oxide niobium- and tantalum-containing materials are reviewed. The main idea consists in the development of methods of a controllable synthesis of a new class of precursors: mono- and bimetallic Low Hydrated Hydroxides (LHH) of niobium and/or tantalum (Nb n Ta1 − n O x (OH)5 − x · mH2O) and use of intermediates on their basis in synthesis of complex oxide phases, with production of materials of high phase and chemical homogeneity and specified granulometric composition.
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Roco, M.C., Broader Societal Issues of Nanotechnology, J. Nanopart. Res., 2003, vol. 5, pp. 181–189.
Tretyakov, Yu.D., Development of Inorganic Chemistry as a Fundamental Base for the Design of New Generations of Functional Materials, Russ. Chem. Rev., 2004, vol. 73, pp. 831–847.
Korotkov, A.S. and Atuchin, V.V., Distribution, Structures and Nonlinear Properties of Noncentrosymmetric Niobates and Tantalates, J. Solid State Chem., 2006, vol. 176, pp. 1177–1182.
Tither, G., Progress in Niobium Markets and Technology 1981–2001, Proc. Niobium Science and Technology: Proceedings of the International Symposium (Orlando, Florida, 2001), Bridgeville: Niobium 2001, 2002.
Ushikubo, T., Recent Topics of Research and Development of Catalysis by Niobium and Tantalum Oxides, Catal. Today, 2000, vol. 57, pp. 331–338.
Titova, V.A., Kozel’, V.E., Slatinskaya, I.G., et. al., Studies of Tantalum Hydroxide Dewatering, Zh. Neorg. Khim., 1976, vol. 21, pp. 308–313.
Nenitsesku, K., Obshchaya khimiya (General Chemistry), Moscow: Mir, 1968.
Drobot, D.V., Chub, A.V., Krokhin, V.A., and Maltsev, N.A., Problemy khlornykh metodov v metallurgii redkikh metallov (Problems of Chlorine Methods Application in Rare Metals Metallurgy), Moscow: Metallurgiya, 1991.
Sakharov, V.V., Korovkina, N.B., Muravlev, Yu.B., and Korshunov, B.G., Studies of the Composition of Amorphous Products of Hydrolysis of Crystalline Niobium Pentachloride, Zh. Neorg. Khim., 1981, vol. 26, pp. 1493–1500.
Sakharov, V.V., Korovkina, N.B., Korshunov, B.G., and Muravlev, Yu.B., Studies of the Composition of Amorphous Tantalum Hydroxide and Hydrated Oxide, Zh. Neorg. Khim., 1983, vol. 28, pp. 1928–1934.
Mambetov, A.A. and Pototskaya, N.P., Stidies of the Composition and Phase Transformation of Niobium Pentoxide, Azer. Khim. Zh., 1959, no. 3, pp. 77–87.
Shcheka, I.A., Lastochkina, A.A., Mityreva, T.T., and Danil’tsev, B.I., Production of Niobium Hydroxide with Low Fluorine Content, Khim. Tekhnol., 1975, vol. 76, no. 1, pp. 9–11.
Jander, G. and Schulz, H., über Amphotere Oxydhydrate, deren Alkalische Lösungen und Feste Salze (Isopolysäuren und Isopolysaure Salze). II. Mittulung: Die Tantalsäure und Einige Ihrer Alkalitantalate, Z. Anorg. Allg. Chem., 1925, vol. 144, pp. 225–247.
Süe, P., Sur la Deshydratation de l’acide Niobique, Compt. Rend. Acad. Sci., 1932, vol. 194, pp. 1745–1747.
Sen, B.K. and Saha, A.V., On the Nature and Structure of “Niobic Acid” and Its Pyrolitic Products: 1H NMR, I.R., Conductivity and Ion Exchange Studies, Mater. Res. Bull., 1981, vol. 16, pp. 923–932.
Sen, B.K. and Saha, A.V., On the Nature and Structure of “Niobic Acid” and its Pyrolitic Products: Part II: Correlation between the Hydrates, the Stoichiometric and the Nonstoichiometric Oxides of Niobium (V), Mater. Res. Bull., 1982, vol. 17, pp. 161–169.
Sathyanarayana, D.N. and Patel, C.C., Hydroxide and Peroxide of Niobium, Z. Anorg. Allg. Chem., 1967, vol. 353, pp. 103–108.
Chalyi, V.P., Gidroksidy metallov (Metal Hydroxides), Kiev: Naukova Dumka, 1972.
Zelikman, A.N., Korshunov, B.G., Elyutin, A.V., and Zakharov, A.M., Niobii i tantal (Niobium and Tantalum), Moscow: Metallurgiya, 1990.
Chalyi, V.P., Ageing Mechanisms of Individual Hydroxides of Metals and Their Systems, Zh. Neorg. Khim., 1963, vol. 8, pp. 269–273.
Hüttig, G.F., and König, A., Das System Niobpentoxyd/Wasser, Z. Anorg. Allg. Chem., 1930, vol. 193, pp. 93–99.
Hüttig, G., Oxide Hydrates and Their Systematics Based on Chemical Affinity Manifestation, Usp. Khim., 1935, vol. 4, pp. 395–427.
Lapitskii, A.V., Simanov, Yu.P., and Yarembash, E.I., On Some Properties of Niobium Pentoxide, Zh. Fiz. Khim., 1952, vol. 16, no. 1, pp. 56–59.
Morozov, I.S., On Chemical Interaction of Niobium Pentoxide with Hydroxides of Rare Earth Metals, Titanium, and Iron, Zh. Neorg. Khim., 1956, vol. 1, pp. 791–798.
Rozhenko, S.P. and Kvashenko, A.P., On Polymorphous Transformation of Niobium Pentoxide, Ukr. Khim. Zh., 1972, vol. 38, pp. 819–821.
Lapitskii, A.V., Simanov, Yu.P., Semenenko, K.N., and Yarembash, E.I., On Some Properties of Tantalum Pentoxide, Vestn. Mosk. Univ., Ser. Fiz.-Mat. Estestv. Nauk, 1954, no. 3, pp. 85–89.
Titova, V.A., Kozel’, V.E., Slatinskaya, I.G., et. al., Studies of Tantalum Hydroxide Dewatering, Zh. Neorg. Khim., 1976, vol. 21, pp. 308–313.
Ivanova, N.E., Sakharov, V.V., and Korovin, S.S., IonExchange Synthesis Based on Low Water Content Niobium Hydroxide, Khim. Tekhnol. Neorg. Proizvod., 1977, vol. 7, no. 1, pp. 53–59.
Pakholkov, V.S., Dvinin, S.G., and Markov, V.F., Sorption of Threeand Five-Valent Arsenic from Aqueous Solutions by Oxyhydrates and Ionrganic Ion-Excangers on Their Basis, Zh. Prikl. Khim., 1980, vol. 53, pp. 280–285.
Nikishina, E.E., Drobot, D.V., Filonenko, V.P., Zibrov, I.P., and Lebedeva, E.N., Crystallization Features of Amorphous Tantalum Pentoxide under Atmospheric and High Pressure, Russ. J. Inorg. Chem., 2002, vol. 47, pp. 10–13.
Nikishina, E.E., Lebedeva, E.N., Drobot, D.V., and Korovin, S.S., Low Hydrated Hydroxides of Niobium and Tantalum as Precursors for Synthesis of Complex Oxides, Izv. Vyssh. Uchebn. Zaved., Tsvetn. Metall., 2000, no. 3, pp. 28–31.
Sakharov, V.V., Ivanova, N.E., Korovin, S.S., and Zakharov, M.A., Topochemical Production of Niobium and Tantalum Hydroxide from Different Compounds, Zh. Neorg. Khim., 1974, vol. 19, pp. 579–584.
Rozovskii, A.Ya., Kinetika topokhimicheskikh reaktsii (Kinetics of Topochemical Reactions), Moscow: Khimiya, 1974.
Sakharov, V.V., Donskaya, T.V., Ivanova, N.E., and Korovin, S.S., Kinetics of Heterogeneous Process of Niobium Hydroxide Formation, in Problemy kinetiki i kataliza: materially vysshikh uchebnykh zavedenii (Kinetics and Catalysis Problems: Transactions of Higher Education Institutions), Ivanovo: Ivanovo Inst. Chem. Technol., 1980, pp. 104–108.
Drobot, D.V. and Korovin, S.S., Controlled Synthesis of Functional Materials Based on Rare Metals, in Osnovnye dostizheniya nauchnykh shkol: ezhegodnyi sbornik (Main Achievement of Science Schools: Anniversary Collection), Moscow: Mosk. Inst. Tonkoi Khim. Tekhnol., 2000, pp. 112–127.
Nikishina, E.E., Lebedeva, E.N., and Drobot, D.V., Controlled Synthesis of Polyniobatotantalates, Russ. J. Inorg. Chem., 2011, vol. 56, pp. 1078–1086.
Drobot, D.V., Nikishina, E.E., Lebedeva, E.N., and Petrakova, O.V., Methods of “Soft” Chemistry in the Technology of Production of Functional Materials Based on Rare Elements of III, V–VIII Groups, Nonferr. Met., no. 3, 21–27 (2011).
Brauer, G., Die Oxyde des Niobs, Z. Anorg. Allg. Chem., 1941, vol. 248, pp. 1–104.
Schäfer, H. and Breil, G., über das System Nb2O5-Ta2O5-NbO2-TaO2-H2O-H2, Z. Anorg. Allg. Chem., 1952, vol. 267, pp. 265–276.
Schäfer, H., Dürkop, A., and Jori, M., über die Affinitätsverältnisse bei der Phasen-Umwandlung im System Nb2O5-Ta2O5, Z. Anorg. Allg. Chem., 1954, vol. 275, pp. 289–300.
Schäfer, H., Gruehn, R., and Schulte, F., Die Modifikationen des Niobpentoxides, Angew. Chem., 1966, vol. 78, pp. 28–41.
Shäfer, M.W. and Roy, R., Polymorphism of Nb2O5, Z. Krist., 1958, vol. 110, pp. 241–248.
Frevel, L.K. and Rinn, H.W., Powder Diffraction Standards for Niobium Pentoxide and Tantalum Pentoxide, Anal. Chem., 1955, vol. 27, pp. 1329–1330.
Holtzberg, F., Reisman, A., Berry, M., and Berkenblit, M., Chemistry of the Group VB Pentoxides. The Polymorphism of Nb2O5, J. Am. Chem. Soc., 1957, vol. 9, pp. 2039–2043.
Reisman, A. and Holtzberg, F., Further Comments on the Polymorphism of Nb2O5. The High Temperature Metastable Phase, J. Am. Chem. Soc., 1959, vol. 81, pp. 3182–3184.
Goldschmidt, H.J., High-Temperature X-Ray Investigation on Niobium Pentoxide and Problems Concerning the Oxidation of Niobium, J. Inst. Met., 1959, vol. 87, pp. 235–239.
Nowotny, H., Benesovsky, F., Rudy, E., and Wittmann, A., Aufbau und Zunderverhalten von Niob-Bor-Silicium-Legierungen, Monatsh. Chem., 1960, vol. 91, pp. 975–990 (1960).
Hicks, W.T., Oxidation of Niobium Monoxide, Trans. Am. Inst. Min. Eng., 1961, vol. 221, pp. 352–356.
Terao, N., Structures des Oxides de Niobium, Jpn. J. Appl. Phys., 1963, vol. 2, pp. 156–174.
Terao, N., Structure des Oxydes de Niobium: la Formation de Strycture du Nb2O5-Γ en Nb2O5-Γ et la Formation du NbO2, Jpn. J. Appl. Phys., 1965, vol. 4, pp. 8–15.
Gatehouse, B.M. and Wadsley, A.D., The Crystal Structure of the High Temperature Form of Niobium Pentoxide, Acta Cryst., 1964, vol. 17, pp. 1545–1554.
Laves, F., Moser, R., and Petter, W., Eine Neue Phase von Niobpentoxyd (Zeta-Nb2O5), Die Naturwissenschaften, 1964, vol. 51, pp. 356–357.
Laves, F., Petter, W., and Wulf, H., Die Kristallstruktur von ξ-Nb2O5, Die Naturwissenschaften, 1964, vol. 51, pp. 633–634.
Laves, F., Moser, R., and Petter, W., Die Kristallstruktur von η-Nb2O5, Die Naturwissenschaften, 1965, vol. 52, pp. 617–618.
Gruehn, R., Eine Weitere Neue Modifickation des Niobpentoxides, J. Less-Common Met., 1966, vol. 11, pp. 119–126.
Hibst, H. and Gruehn, R., Neue Beobachtungen zur Mechanischen und Thermischen Umwandlung von Nioboxiden, Z. Anorg. Allg. Chem., 1978, vol. 40, pp. 137–154.
Chen, W.K. and Swalin, R.A., Studies on the Defect Structure of α -Nb2O5, J. Phys. Chem. Solids, 1966, vol. 27, pp. 57–64.
Mertin, W., Andersson, S., and Gruehn, R., Über die Kristallstruktur von M-Nb2O5, J. Solid State Chem., 1970, vol. 1, pp. 419–424.
Kato, V.K. and Tamura, S., Die Kristallstruktur von T-Nb2O5, Acta Cryst. B, 1975, vol. 31, pp. 673–677 (1975).
Izumi, F. and Kodama, H., Crystallization and Relative Stabilities of Polymorphs of Niobium(V) Oxide under Hydrothermal Conditions, Z. Anorg. Allg. Chem., 1978, vol. 440, 155–167.
Kikuchi, M., Kusaba, K., Bannai, E., Fukuoka, K., Syono, Y., and Hiraga, K., Observation of Shock-Induced Phase of Nb2O5 Single Crystal under High-Resolution Electron Microscopy, Jpn. J. Appl. Phys., 1985, vol. 24, pp. 1600–1606.
Zibrov, I.P., Filonenko, V.P., Werner, P.-E., Marinder, B.-O., and Sundberg, M., A New High-Pressure Modifications of Nb2O5, J. Solid State Chem., vol. 141, pp. 205–211.
Filonenko, V.P. and Zibrov, I.P., Phase Transitions in Oxides M2O5 (M-V, Nb, Ta) at High Pressures and Thermal Stability of New Modifications, Inorg. Mater., 2001, vol. 37, pp. 953–960.
Wasilewski, R. J., The Solubility of Oxygen in the Oxides of Tantalum, J. Am. Chem. Soc., 1953, vol. 75, pp. 1001–1002.
Schäfer, H., Bergner, D., and Gruehn, R., Beiträge zur Chemie der Elemente Niob und Tantal. LXXI. Die Thermodynamische Stabilität der Sieben zwischen 2,00 und 2,50 O/Nb Existierenden Phasen, Z. Anorg. Allg. Chem., 1969, vol. 365, pp. 31–50.
Zaslavskii, A.I., Zvinchuk, R.A., and Tutov, A.G., X-Ray Studies of Ta2O5 Polymorphism, Dokl. Akad. Nauk SSSR, 1955, vol. 104, pp. 409–411.
Reisman, A., Holtzberg, F., Berkenblit, M., and Berry, M., Reaction of the Group VB Pentoxydes with Alkali Oxides and Carbonates. Thermal and X-Ray Phase Diagrams of the System K2O or K2CO3 with Ta2O5, J. Am. Chem. Soc., 1956, vol. 78, pp. 4514–4520.
Harvey, J. and Wilman, H., The Crystallization of Thin Amorphous Tantalum Oxide Films Heated in Air or Vacuo, and the Structure of the Crystalline Oxide, Acta Cryst., 1961, vol. 14, pp. 1278–1281.
Laves, F. and Petter, W., Eine Displazive Umwandlung bei α-Ta2O5, Helv. Phys. Acta, 1964, vol. 37, pp. 617–618.
Terao, N., Structure des Oxides de Tantale, Jpn. J. Appl. Phys., 1967, vol. 6, pp. 21–36.
Mertin, W., Gruehn, R., and Schäfer, H., Neue Beobachtungen zum System TiO2-Ta2O5, J. Solid State Chem., 1970, vol. 1, pp. 425–444.
Roth, R.S., Waring, J.L., and Parker, H.S., Effect of Oxide Additions on the Polymorphism of Tantalum Pentoxide, J. Solid State Chem., 1970, vol. 2, pp. 445–461.
Stephenson, N.C. and Roth, R.S., Structural Systematics in the Binary System Ta2O5-WO3. The Structure of the Low-Temperature Form of Tantalum Oxide L-Ta2O5, Acta Cryst. B, 1971, vol. 27, pp. 1037–1044.
Stephenson, N.C. and Roth, R.S., The Crystal Structure of the High Temperature Form of Ta2O5, J. Solid State Chem., 1971, vol. 3, pp. 145–153.
Plies, V. and Gruehn, R., Zum Thermischen Verhalten Metastabiler H-Ta2O5 — Varianten im System Ta2O5- TiO2, Z. Anorg. Allg. Chem., 1980, vol. 463, pp. 32–44.
Hummel, H.-U., Fackler, R., and Remmert, P., Tantaloxide durch Gasphasenhydrolyse, Druckhydrolyse und Transportreaktion aus 2H-TaS2: Synthesen von TT-Ta2O5 und T-Ta2O5 und Kristallstruktur von T-Ta2O5, Chem. Ber., 1992, vol. 125, pp. 551–556.
Zibrov, I.P., Filonenko, V.P., Sundberg, M., and Werner, P.-E., Structures and Phase Transitions of B-Ta2O5 and Z-Ta2O5: Two High-Pressure Forms of Ta2O5, Acta Cryst. B, 2000, vol. 56, pp. 659–665.
Filonenko, V.P., Zibrov, I.P., Drobot, D.V., and Nikishina, E.E., Structure of a High-Pressure Hydroxide Ta2O5·2/3H2O and a Derivative Metastable Oxide Ta2O5, Russ. J. Inorg. Chem., 2003, vol. 48, pp. 464–471.
Holtzberg, F. and Reisman, A., Sub-Solidus Equilibria in the system Nb2O5-Ta2O5, J. Phys. Chem., 1961, vol. 65, pp. 1192–1196.
Gonzalez, J., Ruiz, C., Pasquevich, D., and Bohé, A., Formation of Niobium-Tantalum Pentoxide Orthorhombic Solid Solutions under Chlorine-Bearing Atmospheres, J. Mater. Sci., 2001, vol. 36, pp. 3299–3311.
Drobot, D., Nikishina, E., Lebedeva, E., Novoselov, A., and Yoshikawa, A., Synthesis of Complex Oxide Phases by Using of Low Hydrated Niobium and Tantalum Hydroxides, Mater. Res. Bull., 2008, vol. 43, pp. 1232–1238.
Shrout, T.R. and Halliyal, A., Preparation of Lead-Based Ferroelectrics Relaxors for Capacitors, Am. Ceram. Soc. Bull., 1987, vol. 66, pp. 704–711.
Swarts, S.L. and Shrout, T.R., Fabrication of Perovskite Lead Magnesium Niobate, Mater. Res. Bull., 1982, vol. 17, pp. 1245–1256.
Sych, A.M. and Golub, A.M., Niobates and Tantalates of 3-Valent Elements, Russ. Chem. Rev., 1977, vol. 46, pp. 210–226.
Arsenyev, P.A., Glushkova, V.B., and Evdokimov, A.A., Tsirkonaty, gafnaty, niobaty, tantalaty i antimonaty (Zirconates, Hafnates, Niobates, Tantalates, and Antimonates), Moscow: Nauka, 1985.
Turova, N.Ya., Turevskaya, E.P., Kessler, V.G., and Yanovskaya, M.I., Khimiya alkoksidov metallov (Metal Alkoxides Chemistry Handbook), Dordrecht: Kluwer, 2001.
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Nikishina, E.E., Lebedeva, E.N. & Drobot, D.V. Niobium- and tantalum-containing oxide materials: Synthesis, properties, and application. Inorg Mater 48, 1243–1260 (2012). https://doi.org/10.1134/S002016851213002X
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DOI: https://doi.org/10.1134/S002016851213002X