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Effect of Eu2O3 doping on the crystallization behavior of BaO-Bi2O3-B2O3 glasses

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Abstract

We gave studied the crystallization behavior of 30BaO · 25Bi2O3 · 45B2O3 glasses doped with Eu2O3 to different levels. At a Eu2O3 content of 7 mol % or higher, the glasses undergo volume crystallization. The only precipitating phase is a solid solution between europium and bismuth oxides. With increasing europium concentration in the glass, the structure of the crystallites changes from cubic to rhombohedral. We have investigated the morphology, physicochemical properties, and luminescence spectra of the glasses and glass-ceramics.

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    A. V. Egorysheva, V. D. Volodin & V. M. Skorikov

  2. Bogatskii Physicochemical Institute, National Academy of Sciences of Ukraine, Lyustdorfskaya doroga 86, Odessa, 65080, Ukraine

    I. V. Berezovskaya & E. V. Zubar’

  3. Institute of Solid State Physics, Bulgarian Academy of Sciences, Tzarigradsko Chaussee Blvd. 72, Sofia, 1784, Bulgaria

    T. Milenov & P. Rafailov

  4. European Polytechnical University, Sv. sv. Kiril i Metodiy str. 23, Pernik, 2300, Bulgaria

    T. Milenov

Authors
  1. A. V. Egorysheva
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  2. V. D. Volodin
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  3. I. V. Berezovskaya
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  4. E. V. Zubar’
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  5. V. M. Skorikov
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  6. T. Milenov
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  7. P. Rafailov
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Correspondence to A. V. Egorysheva.

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Original Russian Text © A.V. Egorysheva, V.D. Volodin, I.V. Berezovskaya, E.V. Zubar’, V.M. Skorikov, T. Milenov, P. Rafailov, 2012, published in Neorganicheskie Materialy, 2012, Vol. 48, No. 9, pp. 1071–1075.

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Egorysheva, A.V., Volodin, V.D., Berezovskaya, I.V. et al. Effect of Eu2O3 doping on the crystallization behavior of BaO-Bi2O3-B2O3 glasses. Inorg Mater 48, 948–952 (2012). https://doi.org/10.1134/S0020168512090051

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  • DOI: https://doi.org/10.1134/S0020168512090051

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