Abstract
An extensive experimental search for the smallest stable gaseous multiply charged anions (MCAs) was pursued. Four penta-atomic dianions, and , were found to be the smallest observable using an electrospray ion source. Photodetachment experiments revealed, however, that and are electronically metastable with negative electron-binding energies. and were found to be electronically stable, but thermodynamically unstable against fragmentation. Lifetimes were estimated using an ion-trap technique for the four observed metastable MCAs, providing further insight into their electronic and thermodynamic stability.
- Received 29 June 1999
DOI:https://doi.org/10.1103/PhysRevLett.83.3402
©1999 American Physical Society