Abstract
We reexamine the density functional theory of laser-induced freezing, i.e., the freezing of a colloidal liquid into crystalline order in the presence of an external periodic modulating potential with its wave vectors tuned to the ordering wave vector in the liquid phase. We show definitively that the initial first order freezing transition (at small ) changes to a continuous one (at large ) via a tricritical point provided the modulation wave vectors are suitably chosen. We also present predictions for the parameter values of the tricritical points for a realistic colloidal system.
- Received 15 October 1993
DOI:https://doi.org/10.1103/PhysRevLett.73.2923
©1994 American Physical Society