Determinants of surface atomic geometry: The CuCl(110) test case

A. Kahn, S. Ahsan, W. Chen, M. Dumas, C. B. Duke, and A. Paton
Phys. Rev. Lett. 68, 3200 – Published 25 May 1992
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Abstract

The atomic geometry of the CuCl(110)-(1×1) surface is determined by dynamical analysis of low-energy electron-diffraction intensities. This surface undergoes a relaxation characterized by a ∼30° Cu-Cl surface bond rotation, a 0.15 Å contraction of the top-to-second layer distance, and a 0.4 Å horizontal displacement of Cl relative to Cu. The relaxation is consistent with the ‘‘universal’’ structure deduced from the analysis of cleavage surface of tetrahedrally coordinated III-V and II-VI compounds, thereby revealing that this featuare of the structure does not depend significntly on the ionicity of the compound.

  • Received 6 February 1992

DOI:https://doi.org/10.1103/PhysRevLett.68.3200

©1992 American Physical Society

Authors & Affiliations

A. Kahn, S. Ahsan, W. Chen, and M. Dumas

  • Department of Electrical Engineering, Princeton University, Princeton, New Jersey 08544

C. B. Duke and A. Paton

  • Xerox Webster Research Center, 800 Phillips Road, Webster, NewYork 14580

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Issue

Vol. 68, Iss. 21 — 25 May 1992

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