Self-diffusion of colloidal particles in a two-dimensional suspension: Are deviations from Fick’s law experimentally observable?

Martin A. van der Hoef, Daan Frenkel, and Anthony J. C. Ladd
Phys. Rev. Lett. 67, 3459 – Published 9 December 1991
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Abstract

Simulations of a colloidal particle suspended in a two-dimensional fluid are reported. The dissipative and fluctuating hydrodynamic forces acting on the particle are modeled by a lattice gas. Our results indicate that large long-time tails are present in both the translational and the rotational velocity correlation functions; these are the first observations of a rotational long-time tail. The strong translational tail leads to an observable renormalization of the diffusion coefficient; our results suggest that experimental observation of the latter effect is possible.

  • Received 26 August 1991

DOI:https://doi.org/10.1103/PhysRevLett.67.3459

©1991 American Physical Society

Authors & Affiliations

Martin A. van der Hoef and Daan Frenkel

  • Foundation for Fundamental Research on Matter (FOM)-Institute for Atomic and Molecular Physics, Kruislaan 407, 1098 SJ Amsterdam, The Netherlands

Anthony J. C. Ladd

  • Lawrence Livermore National Laboratory, Livermore, California 94550

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Vol. 67, Iss. 24 — 9 December 1991

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