Short-time correlations in liquids: Molecular-dynamics simulation of hard spheroids

Julian Talbot, Daniel Kivelson, Gilles Tarjus, Michael P. Allen, Glenn T. Evans, and Daan Frenkel
Phys. Rev. Lett. 65, 2828 – Published 26 November 1990
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Abstract

The velocity and angular velocity autocorrelation functions obtained by molecular-dynamics simulations of liquids composed of hard spheroids indicate the existence of damped oscillations with periods as long as 40 times the mean time between molecular collisions. In addition, little correlation is found between successive collisions. This suggests that the damped oscillations are not due to semicoherent molecular librations in cells.

  • Received 16 April 1990

DOI:https://doi.org/10.1103/PhysRevLett.65.2828

©1990 American Physical Society

Authors & Affiliations

Julian Talbot, Daniel Kivelson, and Gilles Tarjus

  • Department of Chemistry and Biochemistry, University of California, Los Angeles, California 90024

Michael P. Allen

  • H.H. Wills Physics Laboratory, University of Bristol, Bristol BS8 1TL, England

Glenn T. Evans

  • Department of Chemistry, Oregon State University, Corvallis, Oregon 97331

Daan Frenkel

  • (FOM) Fundamenteel Onderzoek der Materie–Institute for Atomic Molecular Physics, P.O. Box 41883, 1009 DB Amsterdam, The Netherlands

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Issue

Vol. 65, Iss. 22 — 26 November 1990

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