New Measurement of the Trace of the Helium Diatom Polarizability from the Collision-Induced, Polarized, Raman Spectrum

Michael H. Proffitt and Lothar Frommhold
Phys. Rev. Lett. 42, 1473 – Published 28 May 1979
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Abstract

Collision-induced Raman spectra of helium at 30 amagats are obtained, with incident beam polarization parallel and perpendicular to the direction of observation. The comparison reveals the presence of a polarized continuum not seen before in any gas. A wave-mechanical computation of this polarized spectrum, utilizing as input an ab initio calculation of the trace of the helium diatom polarizability, agrees with the observation. Thus a second, independent measurement of the isotropic part of the diatom polarizability is obtained.

  • Received 13 March 1979

DOI:https://doi.org/10.1103/PhysRevLett.42.1473

©1979 American Physical Society

Authors & Affiliations

Michael H. Proffitt and Lothar Frommhold

  • University of Texas at Austin, Austin, Texas 78712

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Issue

Vol. 42, Iss. 22 — 28 May 1979

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