Effects of initial correlations on the dynamics of dissipative systems

Eli Pollak, Jiushu Shao, and Dong Hui Zhang
Phys. Rev. E 77, 021107 – Published 7 February 2008

Abstract

The time correlation functions for a Gaussian wave-packet preparation of the dissipative harmonic oscillator evolving from three initial conditions for the heat bath are calculated and compared with each other for Ohmic heat baths. The three initial distributions for the bath are the factorized, partially factorized, and unfactorized distributions. Explicit analytical formulas are derived and then used to study the effect of the three initial distributions on the subsequent dynamics. We find that the transient behavior does not depend sensitively on the initial condition as long as the initial Gaussian wave function of the system is centered at the equilibrium point. Differences become noticeable as the center of the wave packet is significantly shifted from the equilibrium point. These observations justify to some extent the prevalent use of factorized initial conditions for studying real time quantum dynamics in dissipative systems. The total energy in the system is also calculated for the three initial states and its relation to features in the decay is pointed out.

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  • Received 18 October 2007

DOI:https://doi.org/10.1103/PhysRevE.77.021107

©2008 American Physical Society

Authors & Affiliations

Eli Pollak1, Jiushu Shao2, and Dong Hui Zhang3

  • 1Chemical Physics Department, Weizmann Institute of Science, 76100 Rehovoth, Israel
  • 2College of Chemistry, Beijing Normal University, 100875 Beijing, China
  • 3Center for Theoretical and Computational Chemistry and State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China

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Vol. 77, Iss. 2 — February 2008

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