Cohesive energy, stability, and structural transitions in polyelectrolyte bundles

Joseph Rudnick and David Jasnow
Phys. Rev. E 68, 051902 – Published 5 November 2003
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Abstract

A lattice of uniformly charged, infinitesimally thin rods decorated with an ordered array of counterions exhibits anomalous behavior as the spacing between the rods is varied. In particular, the counterion lattice undergoes a sequence of structural shearing or “tilting,” phase transformations as the spacing between the rods decreases. The potential implications of this behavior with respect to the packaging of biologically relevant polyelectrolytic molecules are commented upon.

  • Received 26 July 2002

DOI:https://doi.org/10.1103/PhysRevE.68.051902

©2003 American Physical Society

Authors & Affiliations

Joseph Rudnick

  • Department of Physics and Astronomy, UCLA, Box 951547, Los Angeles, California 90095-1547, USA

David Jasnow

  • Department of Physics and Astronomy, University of Pittsburgh, Pittsburgh, Pennsylvania 15260, USA

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Vol. 68, Iss. 5 — November 2003

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