Exact solutions of the monomer-monomer reaction: Segregation, poisoning, and interface evolution

David S. Sholl and Rex T. Skodje
Phys. Rev. E 53, 335 – Published 1 January 1996
PDFExport Citation

Abstract

The dynamics of the monomer-monomer surface reaction can be defined by an exact, closed set of differential rate equations in the limit of infinite absorption rates. We use these equations to obtain numerically converged ‘‘exact’’ solutions to this model for a variety of situations that have previously been treated with Monte Carlo simulations. In particular, we derive a number of results for spatially inhomogeneous systems that involve an evolving reactive interface. © 1996 The American Physical Society.

  • Received 16 August 1995

DOI:https://doi.org/10.1103/PhysRevE.53.335

©1996 American Physical Society

Authors & Affiliations

David S. Sholl and Rex T. Skodje

  • Program in Applied Mathematics, University of Colorado, Boulder, Colorado 80309-0526
  • Department of Chemistry and Biochemistry, Joint Institute for Laboratory Astrophysics and Program in Applied Mathematics, University of Colorado, Boulder, Colorado 80309-0215

References (Subscription Required)

Click to Expand
Issue

Vol. 53, Iss. 1 — January 1996

Reuse & Permissions
Access Options
Author publication services for translation and copyediting assistance advertisement

Authorization Required


×
×

Images

×

Sign up to receive regular email alerts from Physical Review E

Log In

Cancel
×

Search


Article Lookup

Paste a citation or DOI

Enter a citation
×