Generalized compressibility equation for inhomogeneous fluids at equilibrium

Liudmila A. Pozhar, Keith E. Gubbins, and Jerome K. Percus
Phys. Rev. E 48, 1819 – Published 1 September 1993
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Abstract

A general relation is derived between the pressure tensor in an equilibrated inhomogeneous fluid and the direct correlation function. This relation reduces to the usual compressibility equation for a homogeneous fluid and is to be considered as the generalized compressibility equation. The equation provides a starting point for integral-equation theories and is useful in the rigorous kinetic theory of inhomogeneous fluids.

  • Received 22 April 1993

DOI:https://doi.org/10.1103/PhysRevE.48.1819

©1993 American Physical Society

Authors & Affiliations

Liudmila A. Pozhar and Keith E. Gubbins

  • School of Chemical Engineering, Cornell University, Ithaca, New York 14853

Jerome K. Percus

  • Courant Institute of Mathematical Sciences and Physics Department, New York University, New York, New York 10012

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Issue

Vol. 48, Iss. 3 — September 1993

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