Predicting excitonic gaps of semiconducting single-walled carbon nanotubes from a field theoretic analysis

Robert M. Konik, Matthew Y. Sfeir, and James A. Misewich
Phys. Rev. B 91, 075417 – Published 17 February 2015

Abstract

We demonstrate that a nonperturbative framework for the treatment of the excitations of single-walled carbon nanotubes based upon a field theoretic reduction is able to accurately describe experiment observations of the absolute values of excitonic energies. This theoretical framework yields a simple scaling function from which the excitonic energies can be read off. This scaling function is primarily determined by a single parameter, the charge Luttinger parameter of the tube, which is in turn a function of the tube chirality, dielectric environment, and the tube's dimensions, thus expressing disparate influences on the excitonic energies in a unified fashion. We test this theory explicitly on the data reported by Dukovic et al. [Nano Lett. 5, 2314 (2005)] and Sfeir et al. [Phys. Rev. B 82, 195424 (2010)] and so demonstrate the method works over a wide range of reported excitonic spectra.

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  • Received 9 March 2014
  • Revised 16 December 2014

DOI:https://doi.org/10.1103/PhysRevB.91.075417

©2015 American Physical Society

Authors & Affiliations

Robert M. Konik1, Matthew Y. Sfeir2, and James A. Misewich1

  • 1Condensed Matter Physics and Material Science Department, Brookhaven National Laboratory, Upton, New York 11973, USA
  • 2Center for Functional Nanomaterials, Brookhaven National Laboratory, Upton, New York 11973, USA

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Issue

Vol. 91, Iss. 7 — 15 February 2015

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