Full-counting statistics for molecular junctions: Fluctuation theorem and singularities

Y. Utsumi, O. Entin-Wohlman, A. Ueda, and A. Aharony
Phys. Rev. B 87, 115407 – Published 8 March 2013

Abstract

We study the full-counting statistics of charges transmitted through a single-level quantum dot weakly coupled to a local Einstein phonon which causes fluctuations in the dot energy. An analytic expression for the cumulant generating function, accurate up to second order in the electron-phonon coupling and valid for finite voltages and temperatures, is obtained in the extended wide-band limit. The result accounts for nonequilibrium phonon distributions induced by the source-drain bias voltage, and concomitantly satisfies the fluctuation theorem. Extending the counting field to the complex plane, we investigate the locations of possible singularities of the cumulant generating function, and exploit them to identify regimes in which the electron transfer is affected differently by the coupling to the phonons. Within a large-deviation analysis, we find a kink in the probability distribution, analogous to a first-order phase transition in thermodynamics, which would be a unique hallmark of the electron-phonon correlations. This kink reflects the fact that although inelastic scattering by the phonons once the voltage exceeds their frequency can scatter electrons opposite to the bias, this will never generate current flowing against the bias at zero temperature, in accordance with the fluctuation theorem.

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  • Received 6 October 2012

DOI:https://doi.org/10.1103/PhysRevB.87.115407

©2013 American Physical Society

Authors & Affiliations

Y. Utsumi1,2,*, O. Entin-Wohlman3,4,2, A. Ueda5, and A. Aharony3,4,2

  • 1Department of Physics Engineering, Faculty of Engineering, Mie University, Tsu, Mie, 514-8507, Japan
  • 2Kavli Institute for Theoretical Physics China, CAS, Beijing 100190, China
  • 3Physics Department, Ben Gurion University, Beer Sheva 84105, Israel
  • 4Raymond and Beverly Sackler School of Physics and Astronomy, Tel Aviv University, Tel Aviv 69978, Israel
  • 5Faculty of Pure and Applied Sciences, Division of Applied Physics, University of Tsukuba, Tsukuba, Ibaraki, 305-8573, Japan

  • *utsumi@phen.mie-u.ac.jp

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Vol. 87, Iss. 11 — 15 March 2013

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