Abstract
NiO octahedral tilts in the LaNiO/SrTiO superlattices are quantified using position averaged convergent beam electron diffraction in scanning transmission electron microscopy. It is shown that maintaining oxygen octahedra connectivity across the interface controls the octahedral tilts in the LaNiO layers, their lattice parameters, and their transport properties. Unlike films and layers that are connected on one side to the substrate, subsequent LaNiO layers in the superlattice exhibit a relaxation of octahedral tilts towards bulk values. This relaxation is facilitated by tilts in the SrTiO layers and is correlated with the conductivity enhancement of the LaNiO layers in the superlattices relative to individual films.
- Received 26 November 2012
DOI:https://doi.org/10.1103/PhysRevB.87.060101
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