We time resolve the event of singlet separation into free carriers in an oligofluorene using femtosecond field assisted pump-probe technique. Steady state photoinduced absorption (PA) measurements have also been employed to identify triplet absorption $(T_1-T_n)$ in the spectral region of $1.8\mathrm{eV}$. As a result of an applied electric field of $2.2\mathrm{MV}∕\mathrm{cm}$ singlets are observed to undergo a dissociation process consisting of first singlet splitting into bound polaron pairs and second further dissociation of polaron pairs into free carriers. Subsequent free carrier recombination yields a new population of singlets and triplets. Our results suggest that nongeminate recombination leads to the formation of 35% singlets and 65% triplets.

• Received 9 September 2004

DOI:https://doi.org/10.1103/PhysRevB.71.155207