Abstract
Polarized Raman spectra of single and polycrystalline ceramic samples were studied as a function of temperature. For the rhombohedral and the observed Raman peaks were associated with modes arising from the folding of the Brillouin zone under lattice deformation. For the orthorhombic the Raman spectra are consistent with the structure and show an anomalous softening of the 494 and 604 modes below the antiferromagnetic ordering temperature K. Polycrystalline samples of show a dramatic change of the Raman spectra between 100 and 160 K, which was associated with the increase of the orthorhombic distortion observed by others for K. Other single crystals, with small orthorhombic distortions, show Raman spectra which are similar to those observed in the rhombohedral samples.
- Received 24 February 1998
DOI:https://doi.org/10.1103/PhysRevB.58.11435
©1998 American Physical Society