Abstract
Hollow atoms in which the shell is empty while the outer shells are populated allow studying a variety of important and unusual properties of atoms. The diagram x-ray emission lines of such atoms, the hypersatellites (HSs), were measured for the transition metals, , with a high energy resolution using photoexcitation by monochromatized synchrotron radiation. Good agreement with ab initio relativistic multiconfigurational Dirac-Fock calculations was found. The measured HS intensity variation with the excitation energy yields accurate values for the excitation thresholds, excludes contributions from shake-up processes, and indicates domination near threshold of a nonshake process. The variation of the HS shifts from the diagram line , the splitting, and the intensity ratio, derived from the measurements, are also discussed with a particular emphasis on the QED corrections and Breit interaction.
3 More- Received 15 December 2008
DOI:https://doi.org/10.1103/PhysRevA.79.062511
©2009 American Physical Society