Calculation of cross sections for vibrational excitation and dissociative attachment in electron collisions with HBr and DBr

Jiří Horáček and Wolfgang Domcke
Phys. Rev. A 53, 2262 – Published 1 April 1996
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Abstract

The nonlocal resonance model developed earlier for the description of low-energy inelastic and reactive electron-HCl collisions has been adapted to the electron-HBr collision system. The parameters of the model have been determined by fitting the eigenphase sum in the fixed-nuclei approximation to the data of an ab initio R-matrix calculation of Morgan, Burke, and collaborators. The Schwinger-Lanczos method has been employed to solve the nuclear scattering problem with a nonlocal, complex, and energy-dependent effective potential. Fully converged cross sections have been obtained on a dense grid of energies for many vibrational excitation, deexcitation, and dissociative channels in both HBr and DBr. The computed cross sections are generally in good agreement with experiment as far as data are available. © 1996 The American Physical Society.

  • Received 22 June 1995

DOI:https://doi.org/10.1103/PhysRevA.53.2262

©1996 American Physical Society

Authors & Affiliations

Jiří Horáček

  • Department of Theoretical Physics
  • Faculty of Mathematics and Physics, Charles University Prague
  • V Holešovičkách 2, 180 00 Praha 8
  • Czech Republic

Wolfgang Domcke

  • Institute of Physical and Theoretical Chemistry
  • Technical University Munich
  • D-85748 Garching, Germany

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Issue

Vol. 53, Iss. 4 — April 1996

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