Phase behavior of disklike hard-core mesogens

J. A. C. Veerman and D. Frenkel
Phys. Rev. A 45, 5632 – Published 1 April 1992
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Abstract

We report a computer-simulation study of a system of ‘‘hard cut spheres,’’ oblate particles that are obtained by slicing off the top and bottom caps of a sphere at a distance L/2 from the equatorial plane. This system serves as a model for a disklike mesogen. The phase behavior of this system is found to be strongly dependent on the length-to-width ratio (L/D) of the particles. In addition to isotropic and solid phases, we find nematic and columnar phases for L/D=0.1. For L/D=0.2 we find a columnar phase, and a phase with cubic orientational order but no translational order. For L/D=0.3, only the isotropic fluid and the solid are stable. Where possible, we have located the phase transitions.

  • Received 4 December 1991

DOI:https://doi.org/10.1103/PhysRevA.45.5632

©1992 American Physical Society

Authors & Affiliations

J. A. C. Veerman and D. Frenkel

  • FOM—Institute for Atomic and Molecular Physics, Kruislaan 407, 1098 SK Amsterdam, The Netherlands

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Issue

Vol. 45, Iss. 8 — April 1992

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