Semiclassical quantization via adiabatic switching. I. Choice of tori and initial conditions for two-dimensional systems

Jakub Zakrzewski, Subhash Saini, and Howard S. Taylor
Phys. Rev. A 38, 3877 – Published 1 October 1988
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Abstract

A general theoretical base and a general strategy for implementing semiclassical quantization using the adiabatic-switching method are presented for two-dimensional systems. The method proposed does not depend on specialized coordinates, trajectory, or surfaces-of-section studies and is generalizable to multidimensional systems. The choice of the initial tori for the switching procedure is accomplished by simple diagonalizations of small-dimensional matrix representations of invariant operators obtained from perturbation theory. The method gives quantum energies at a useful level of accuracy for the vast majority of states in many of the well-known nonresonant and resonant Hamiltonian cases. Many eigenvalues previously thought unobtainable when the adiabatic-switching method is used are obtained in a quite simple manner.

  • Received 24 March 1988

DOI:https://doi.org/10.1103/PhysRevA.38.3877

©1988 American Physical Society

Authors & Affiliations

Jakub Zakrzewski

  • Department of Chemistry, University of Southern California, Los Angeles, California 90089-0482

Subhash Saini

  • Theoretical Atomic and Molecular Physics Group (L-417), Department of Physics, Lawrence Livermore National Laboratory, University of California, P.O. Box 808, Livermore, California 94550

Howard S. Taylor

  • Department of Chemistry, University of Southern California, Los Angeles, California 90089-0482

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Vol. 38, Iss. 8 — October 1988

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