Annihilation kinetics in the one-dimensional ideal gas

Yves Elskens and Harry L. Frisch
Phys. Rev. A 31, 3812 – Published 1 June 1985
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Abstract

We consider the annihilation reaction A+A→0 on the real line with an initial equilibrium distribution of particles A (points or rods); the particles move freely before annihilating, with independent initial velocities. For the dichotomic distribution of velocities P(v=c)=1-P(v=-c)=p, we determine the fraction S(t) of particles surviving at time t: (1) If p=(1/2), S(t)∼t1/2 by a central-limit effect; (2) if p≠(1/2), S(t)∼‖2p-1‖+At3/2exp(-Bt) with known constants A and B. We also determine the asymptotic spatial distribution of surviving particles. From these results we derive some bounds on the decay of S(t) for other velocity distributions, and we compare them to the decay of S(t) for diffusive (Brownian) motion.

  • Received 10 December 1984

DOI:https://doi.org/10.1103/PhysRevA.31.3812

©1985 American Physical Society

Authors & Affiliations

Yves Elskens

  • Service de Chimie-Physique II, Code Postal No. 231, Université Libre de Bruxelles, Boulevard du Triomphe, B-1050 Bruxelles, Belgium

Harry L. Frisch

  • Department of Chemistry, State University of New York at Albany, 1400 Washington Avenue, Albany, New York 12222

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Vol. 31, Iss. 6 — June 1985

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