Abstract
The magnetic vibrational circular dichroism (MVCD) spectra of the E-symmetry, modes of , , , and are presented. In each case, an MVCD A term indicating a first order vibrational Zeeman effect is observed. The vibrational g values for the mode of these haloforms were determined for the first time by moment analysis of the MVCD and absorption spectra. A partially charged ‘‘elastic bar’’ model is proposed to qualitatively explain the observed MVCD A terms.
- Received 8 January 1993
DOI:https://doi.org/10.1103/PhysRevLett.71.979
©1993 American Physical Society