Unusually Large Franz-Keldysh Oscillations at Ultraviolet Wavelengths in Single-Walled Carbon Nanotubes

Moon-Ho Ham, Byung-Seon Kong, Woo-Jae Kim, Hee-Tae Jung, and Michael S. Strano
Phys. Rev. Lett. 102, 047402 – Published 30 January 2009
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Abstract

We report large electroabsorption susceptibilities in the ultraviolet region for single-walled carbon nanotubes (SWNT) supported on quartz that are approximately 103 larger than the highest values reported to date for any system. The oscillatory behavior is described using a convolution of Airy functions in photon energy ascribing the effect to Franz-Keldysh oscillations. The metallic and semiconducting SWNT composition is varied, and it is shown that the confinement energy correlates with the average band gap for semiconducting SWNT in the film. The large susceptibilities arise from a subpercolated network of metallic SWNT that enhances the local electric field.

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  • Received 15 May 2008

DOI:https://doi.org/10.1103/PhysRevLett.102.047402

©2009 American Physical Society

Authors & Affiliations

Moon-Ho Ham1, Byung-Seon Kong1,2, Woo-Jae Kim1, Hee-Tae Jung2, and Michael S. Strano1,*

  • 1Department of Chemical Engineering, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, USA
  • 2Department of Chemical and Biomolecular Engineering, Korea Advanced Institute of Science and Technology, Daejeon 305-701, Korea

  • *To whom correspondence should be addressed: strano@mit.edu

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Issue

Vol. 102, Iss. 4 — 30 January 2009

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