Solution to the plateau problem in the Green-Kubo formula

Pep Español, J. A. de la Torre, and D. Duque-Zumajo
Phys. Rev. E 99, 022126 – Published 19 February 2019

Abstract

Transport coefficients appearing in Markovian dynamic equations for coarse-grained variables have microscopic expressions given by Green-Kubo formulas. These formulas may suffer from the well-known plateau problem. The problem arises because the Green-Kubo running integrals decay as the correlation of the coarse-grained variables themselves. The usual solution is to resort to an extreme timescale separation, for which the plateau problem is minor. Within the context of Mori projection operator formulation, we offer an alternative expression for the transport coefficients that is given by a corrected Green-Kubo expression that has no plateau problem by construction. The only assumption is that the Markovian approximation is valid in such a way that transport coefficients can be defined, even in the case that the separation of timescales is not extreme.

  • Received 17 November 2018

DOI:https://doi.org/10.1103/PhysRevE.99.022126

©2019 American Physical Society

Physics Subject Headings (PhySH)

Statistical Physics & Thermodynamics

Authors & Affiliations

Pep Español*, J. A. de la Torre, and D. Duque-Zumajo

  • Departamento de Física Fundamental, Universidad Nacional de Educación a Distancia, Aptdo. 60141 E-28080, Madrid, Spain

  • *Corresponding author: pep@fisfun.uned.es

Article Text (Subscription Required)

Click to Expand

References (Subscription Required)

Click to Expand
Issue

Vol. 99, Iss. 2 — February 2019

Reuse & Permissions
Access Options
Author publication services for translation and copyediting assistance advertisement

Authorization Required


×
×

Images

×

Sign up to receive regular email alerts from Physical Review E

Log In

Cancel
×

Search


Article Lookup

Paste a citation or DOI

Enter a citation
×