• Rapid Communication

Aging in glassy polymer–liquid-crystal layers

Krassimira Antonova, Kostyantyn Slyusarenko, Oleksandr Buluy, Christophe Blanc, Stéphane Joly, Yuriy Reznikov, and Maurizio Nobili
Phys. Rev. E 83, 050701(R) – Published 16 May 2011

Abstract

We present in this Rapid Communication experimental evidence of an acceleration of the zenithal easy-axis dynamics of a nematic liquid crystal (NLC) with the age of a NLC-polymer layer. The comparison with other hard alignment layers strongly indicates that the polymer softness and its ability to reorient in the nematic ordering field is at the origin of the measured dynamics. The unusual acceleration of the dynamics with the polymer age is discussed in terms of this unique coupling with the NLC order. The NLC behaves like a physical plasticizer as a result of the coupling between the NLC and the polymer orders.

    • Received 4 November 2010

    DOI:https://doi.org/10.1103/PhysRevE.83.050701

    ©2011 American Physical Society

    Authors & Affiliations

    Krassimira Antonova1,2, Kostyantyn Slyusarenko1,3, Oleksandr Buluy1,3, Christophe Blanc1, Stéphane Joly4, Yuriy Reznikov3, and Maurizio Nobili1

    • 1Laboratoire des Colloïdes, Verres et Nanomatériaux, Université Montpellier II/CNRS, Place Eugène Bataillon, F-34090 Montpellier, France
    • 2Institute of Solid State Physics, Bulgarian Academy of Sciences, Boulevard Tzarigradsko Chaussee 72, Sofia 1784, Bulgaria
    • 3Institute of Physics, National Academy of Sciences of Ukraine, Prospect Nauki 46, Kyiv 03039, Ukraine
    • 4Nemoptic LCD Advanced Technology, 1, rue Guynemer F-78114 Magny les Hameaux, France

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    Issue

    Vol. 83, Iss. 5 — May 2011

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