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Simulations of dynamics and viscoelasticity in highly entangled solutions of semiflexible rods

Shriram Ramanathan and David C. Morse
Phys. Rev. E 76, 010501(R) – Published 6 July 2007

Abstract

Brownian dynamics simulations are used to study highly entangled solutions of semiflexible polymers. Bending fluctuations of semiflexible rods are significantly affected by entanglement only above a concentration c**, where c**103L3 for chains of length L similar to their persistence length. For c>c**, the tube radius Re approaches a dependence Rec35 and the linear viscoelastic response develops an elastic plateau that is absent for c<c**. Experiments on isotropic solutions of F-actin are shown to span concentrations near c** for which the predicted asymptotic scaling of the plateau modulus, Gc75, is not yet valid.

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  • Received 22 January 2007

DOI:https://doi.org/10.1103/PhysRevE.76.010501

©2007 American Physical Society

Authors & Affiliations

Shriram Ramanathan and David C. Morse*

  • Department of Chemical Engineering and Materials Science, University of Minnesota, Minneapolis, Minnesota 55455, USA

  • *morse@cems.umn.edu

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Vol. 76, Iss. 1 — July 2007

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