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Light scattering enhancement in an aqueous solution of spermine-induced fractal J-aggregate composite

Norberto Micali, Valentina Villari, Luigi Monsù Scolaro, Andrea Romeo, and Maria Angela Castriciano
Phys. Rev. E 72, 050401(R) – Published 21 November 2005

Abstract

We performed an experimental investigation on the scattering and extinction properties of an aqueous solution of spermine-induced fractal J aggregates, constituted by porphyrin molecules. In analogy with nanostructured particle composites, the dipolar moments of different porphyrins, not belonging to the J aggregates, are coupled and generate a strong light scattering enhancement. Both the enhanced scattered intensity and the imaginary part of the polarizability of the system obey scaling laws with the optical spectral dimension d0=0.3.

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  • Received 13 December 2004

DOI:https://doi.org/10.1103/PhysRevE.72.050401

©2005 American Physical Society

Authors & Affiliations

Norberto Micali* and Valentina Villari

  • CNR, Istituto per i Processi Chimico-Fisici, sezione Messina, Via La Farina 237, I-98123 Messina, Italy

Luigi Monsù Scolaro, Andrea Romeo, and Maria Angela Castriciano

  • Dipartimento di Chimica Inorganica, Chimica Analitica e Chimica Fisica, Università di Messina Salita Sperone 31, I-98166 Villaggio S. Agata, Messina, Italy

  • *Electronic address: micali@me.cnr.it
  • Electronic address: monsu@chem.unime.it

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Issue

Vol. 72, Iss. 5 — November 2005

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