Isotropic-cholesteric transition in liquid-crystalline gels

Robert A. Pelcovits and Robert B. Meyer
Phys. Rev. E 66, 031706 – Published 23 September 2002
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Abstract

In a nematic gel, the appearance of nematic order is accompanied by a spontaneous elongation of the gel parallel to the nematic director. If such a gel is made chiral, it has a tendency to form a cholesteric helical texture, in which local elongation of the gel parallel to the nematic director is suppressed due to the requirement of elastic compatibility. We show that a conical helix in which the director makes an oblique angle with respect to the helix axis serves as an energy minimizing compromise between the competing tendencies for elongation and twisting. We find the dependence of the helical cone angle and pitch on the strength of the chirality, and determine the change in sample shape at the isotropic to cholesteric phase transition.

  • Received 14 June 2002

DOI:https://doi.org/10.1103/PhysRevE.66.031706

©2002 American Physical Society

Authors & Affiliations

Robert A. Pelcovits

  • Department of Physics, Brown University, Providence, Rhode Island 02912

Robert B. Meyer

  • The Martin Fisher School of Physics, Brandeis University, Waltham, Massachusetts 02254-9110

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Vol. 66, Iss. 3 — September 2002

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