Merit of ground-state electronegativities; a reply to ‘‘Comments on ‘Introduction to the chemistry of fractionally charged atoms: Electronegativity’ ’’

Klaus S. Lackner and George Zweig
Phys. Rev. D 36, 1562 – Published 1 September 1987
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Abstract

The arguments presented in the Comment by Liebman and Huheey are shown to be incorrect. The operational equivalence of Mulliken ground-state electronegativities and Pauling electronegativities is demonstrated for neutral atoms. It is shown that ground-state electronegativities and valence-state electronegativities for both neutral atoms and ions are also operationally equivalent. A single electronegativity scale based on Mulliken ground-state electronegativities may therefore be used for neutral atoms, ions, and fractionally charged atoms, as originally implied in the paper by Lackner and Zweig.

  • Received 30 June 1986

DOI:https://doi.org/10.1103/PhysRevD.36.1562

©1987 American Physical Society

Authors & Affiliations

Klaus S. Lackner and George Zweig

  • Theory Division, Los Alamos National Laboratory, Los Alamos, New Mexico 87545

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Issue

Vol. 36, Iss. 5 — 1 September 1987

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