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Selection rules for one- and two-photon absorption by excitons in carbon nanotubes

Eduardo B. Barros, Rodrigo B. Capaz, Ado Jorio, Georgii G. Samsonidze, Antonio G. Souza Filho, Sohrab Ismail-Beigi, Catalin D. Spataru, Steven G. Louie, Gene Dresselhaus, and Mildred S. Dresselhaus
Phys. Rev. B 73, 241406(R) – Published 26 June 2006

Abstract

Recent optical absorption and emission experiments showed that the lower energy optical transitions in carbon nanotubes are excitonic in nature, as predicted by theory. These experiments were based on the symmetry aspects of free electron-hole states and bound excitonic states. The present work shows, however, that group theory does not predict the selection rules needed to explain the two photon experiments. We obtain the symmetries and selection rules for the optical transitions of excitons in single-wall carbon nanotubes within the approach of the group of the wave vector, thus providing important information for the interpretation of theoretical and experimental optical spectra of these materials.

  • Figure
  • Received 20 April 2006

DOI:https://doi.org/10.1103/PhysRevB.73.241406

©2006 American Physical Society

Authors & Affiliations

Eduardo B. Barros1,2, Rodrigo B. Capaz3,4, Ado Jorio5, Georgii G. Samsonidze2, Antonio G. Souza Filho1, Sohrab Ismail-Beigi6, Catalin D. Spataru7,8, Steven G. Louie7,8, Gene Dresselhaus9, and Mildred S. Dresselhaus2

  • 1Departamento de Física, Universidade Federal do Ceará, Fortaleza, Ceará, CEP 60455-760, Brazil
  • 2Department of Electrical Engineering and Computer Science, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139-4307, USA
  • 3Instituto de Física, Universidade Federal do Rio de Janeiro, Caixa Postal 68528, Rio de Janeiro, Rio de Janeiro 21941-972, Brazil
  • 4Divisão de Metrologia de Materiais, Instituto Nacional de Metrologia, Normalização e Qualidade Industrial—Inmetro, R. Nossa Senhora das Graças 50, Xerém, Duque de Caxias, Rio de Janeiro 25245-020, Brazil
  • 5Departamento de Física, Universidade Federal de Minas Gerais, Belo Horizonte, Minas Gerais, 30123-970, Brazil
  • 6Department of Applied Physics, Yale University, New Haven, Connecticut 06520, USA
  • 7Department of Physics, University of California at Berkeley, Berkeley, California 94720, USA
  • 8Materials Science Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720, USA
  • 9Francis Bitter Magnet Laboratory, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139-4307, USA

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Issue

Vol. 73, Iss. 24 — 15 June 2006

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