Off-diagonal disorder and activation energy of high-field hopping motion

Yu. N. Gartstein and E. M. Conwell
Phys. Rev. B 51, 6947 – Published 15 March 1995
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Abstract

Monte Carlo simulations of the hopping transport of charge carriers in model disordered systems at high fields are performed. Diagonal disorder is represented by a Gaussian density of states while binary bond disorder is used as a model of off-diagonal disorder. Diagonal disorder and off-diagonal disorder are shown to act synergetically on the hopping motion at high fields. It is demonstrated that, contrary to the usual assumption, off-diagonal disorder can significantly affect the activation energy of the hopping transport.

  • Received 14 November 1994

DOI:https://doi.org/10.1103/PhysRevB.51.6947

©1995 American Physical Society

Authors & Affiliations

Yu. N. Gartstein and E. M. Conwell

  • Center for Photoinduced Charge Transfer, Chemistry Department, University of Rochester, Rochester, New York 14627
  • Xerox Corporation, Wilson Center for Research and Technology, 114-40D Webster, New York 14580

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Vol. 51, Iss. 11 — 15 March 1995

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