Low-density limit of the correlation energy in the random-phase approximation for charged particles of arbitrary statistics

John P. Perdew and Hugh E. DeWitt
Phys. Rev. B 46, 12748 – Published 15 November 1992
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Abstract

Within the random-phase approximation (RPA) or ring sum, the ground-state correlation energy for a uniform gas of charged particles with density parameter rs tends as rs→∞ to (-0.803 Ry) rs3/4. This limit holds for fermions, as for bosons and distinguishable particles. For electrons, the next term in the low-density expansion (of order rs1) cancels the exchange energy. Corrections to RPA must cancel the rs3/4 term, and can modify the rs1 term.

  • Received 3 August 1992

DOI:https://doi.org/10.1103/PhysRevB.46.12748

©1992 American Physical Society

Authors & Affiliations

John P. Perdew

  • Department of Physics and Quantum Theory Group, Tulane University, New Orleans, Louisiana 70118

Hugh E. DeWitt

  • Lawrence Livermore National Laboratory, Livermore, California 94550

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Vol. 46, Iss. 19 — 15 November 1992

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