Strong Local Field Enhancement of Raman Scattering Observed in Metal-Dielectric Gratings due to Vertical Fabry-Perot Modes of Surface Plasmon Polaritons

Dmitrii A. Gromyko, Sergey A. Dyakov, Nikolay A. Gippius, Thomas Weiss, Sergei G. Tikhodeev, Anna S. Astrakhantseva, Yana V. Fedotova, Victor V. Solovyev, and Igor V. Kukushkin
Phys. Rev. Applied 17, 024015 – Published 4 February 2022

Abstract

The height dependence of Raman light scattering on organic molecules deposited onto thick one-dimensional metal-dielectric gratings is investigated theoretically and experimentally. We observe oscillations of the intensity of Raman light scattering as a function of the height of the metastructure’s strips and demonstrate that these oscillations are explicitly associated with a type of Fabry-Perot effect. We show that the intensity of surface-enhanced Raman scattering can be additionally increased by local field enhancement (by an order of magnitude) at resonances of both pump and Stokes as well as anti-Stokes frequency, due to coupling of the surface plasmon polaritons on the top and bottom metal parts of the gratings via the vertical Fabry-Perot resonances over their middle dielectric part. A semianalytical one-mode model to describe the effect qualitatively is proposed. A significant deviation of the dispersion of Fabry-Perot-coupled plasmon polaritons from the surface-plasmon-polariton dispersion just folded into the first Brillouin zone is demonstrated.

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  • Received 20 October 2021
  • Revised 3 December 2021
  • Accepted 11 January 2022

DOI:https://doi.org/10.1103/PhysRevApplied.17.024015

© 2022 American Physical Society

Physics Subject Headings (PhySH)

Condensed Matter, Materials & Applied PhysicsAtomic, Molecular & Optical

Authors & Affiliations

Dmitrii A. Gromyko1,2,3,*, Sergey A. Dyakov1, Nikolay A. Gippius1, Thomas Weiss4,5, Sergei G. Tikhodeev2,3, Anna S. Astrakhantseva6,7, Yana V. Fedotova6, Victor V. Solovyev6, and Igor V. Kukushkin6

  • 1Skolkovo Institute of Science and Technology, Nobel Street 3, Moscow 121205, Russia
  • 2Faculty of Physics, Lomonosov Moscow State University, Leninskiye Gory 1-2, Moscow 119991, Russia
  • 3A. M. Prokhorov General Physics Institute, RAS, Vavilova 38, Moscow 119991, Russia
  • 44th Physics Institute and SCoPE, University of Stuttgart, Pfaffenwaldring 57, Stuttgart 70569, Germany
  • 5Institute of Physics, University of Graz, and NAWI Graz, Universitätsplatz 5, Graz 8111, Austria
  • 6Institute of Solid State Physics RAS, Chernogolovka, Russia
  • 7Moscow Institute of Physics and Technology, Institutskiy pereulok 9, Moscow Region 141701, Russia

  • *Dmitrii.Gromyko@skoltech.ru

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Vol. 17, Iss. 2 — February 2022

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