Equation of state for parallel hard spherocylinders

Reinhard Hentschke, Mark P. Taylor, and Judith Herzfeld
Phys. Rev. A 40, 1678 – Published 1 August 1989
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Abstract

A recent model for positional ordering in systems of monodisperse parallel hard spherocylinders is used to calculate the pressure over the entire range of densities and cylinder axial ratios. Reasonable quantitative agreement with Monte Carlo data is obtained for the full spectrum of nematic, smectic, columnar, and crystalline order. Analytical expressions are also given for the characteristic lengths of the ordering in these phases.

  • Received 6 February 1989

DOI:https://doi.org/10.1103/PhysRevA.40.1678

©1989 American Physical Society

Authors & Affiliations

Reinhard Hentschke

  • Department of Chemistry, Brandeis University, Waltham, Massachusetts 02254-9110

Mark P. Taylor

  • Department of Physics and Department of Chemistry, Brandeis University, Waltham, Massachusetts 02254-9110

Judith Herzfeld

  • Department of Chemistry, Brandeis University, Waltham, Massachusetts 02254-9110

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Vol. 40, Iss. 3 — August 1989

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