Hypernetted-chain approximation for three- and four-body correlations in simple fluids

F. J. Pinski and C. E. Campbell
Phys. Rev. A 33, 4232 – Published 1 June 1986
PDFExport Citation

Abstract

New approximate integral equations for the three- and four-body correlation functions and structure functions are derived. These approximations are based on the hypernetted-chain resummation. The equation for the three-body correlation function satisfies a self-consistency condition, the Born-Green-Yvon equation, and has the Kirkwood superposition approximation as the leading or nonhomogeneous term. Similarly, the new approximation for the third-order structure function has the convolution approximation as its leading term. In addition to the formalism, numeric solutions are presented for a Lennard-Jones system corresponding to argon at its triple point and at room temperature (with its triple-point density). At this high density, the integral equations give results significantly different from their leading terms.

  • Received 21 November 1985

DOI:https://doi.org/10.1103/PhysRevA.33.4232

©1986 American Physical Society

Authors & Affiliations

F. J. Pinski

  • Department of Physics, University of Cincinnati, Cincinnati, Ohio 45221

C. E. Campbell

  • School of Physics and Astronomy, University of Minnesota, Minneapolis, Minnesota 55455

References (Subscription Required)

Click to Expand
Issue

Vol. 33, Iss. 6 — June 1986

Reuse & Permissions
Access Options
Author publication services for translation and copyediting assistance advertisement

Authorization Required


×
×

Images

×

Sign up to receive regular email alerts from Physical Review A

Log In

Cancel
×

Search


Article Lookup

Paste a citation or DOI

Enter a citation
×