Comment on “Monte Carlo study of structural ordering in charged colloids using a long-range attractive interaction”

David G. Grier and John C. Crocker
Phys. Rev. E 61, 980 – Published 1 January 2000
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Abstract

A recent theoretical analysis [B. V. R. Tata and N. Ise, Phys. Rev. E 58, 2237 (1998)] of interactions and phase transitions in charge-stabilized colloidal suspensions made reference to our previously published measurements [J. C. Crocker and D. G. Grier, Phys. Rev. Lett. 73, 352 (1994); 77, 1897 (1996); A. E. Larson and D. G. Grier, Nature (London) 385, 230 (1997)] of colloidal interactions. Tata and Ise claim that our measurements cannot distinguish between predictions of the Derjaguin, Landau, Verwey, and Overbeek (DLVO) theory and those of the competing theory due to Sogami and Ise (SI). We demonstrate that the DLVO theory accurately describes the measured interactions between isolated pairs of like-charged spheres, while the SI theory fails both quantitatively and qualitatively to describe our data.

  • Received 2 November 1998

DOI:https://doi.org/10.1103/PhysRevE.61.980

©2000 American Physical Society

Authors & Affiliations

David G. Grier1 and John C. Crocker2

  • 1The James Franck Institute and Department of Physics, The University of Chicago, 5640 South Ellis Avenue, Chicago, Illinois 60637
  • 2The Department of Physics and Astronomy, The University of Pennsylvania, 209 South 33rd Street, Philadelphia, Pennsylvania 19104

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Vol. 61, Iss. 1 — January 2000

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