Abstract
Pressure-induced phase transformations have been found in CuGa and AgGa by high-pressure x-ray-diffraction studies, using the energy dispersion technique. CuGa transforms from the chalcopyrite to the NaCl type near 16 GPa. AgGa undergoes three pressure-induced phase changes: (1) from chalcopyrite to a hexagonal lattice near 5 GPa, (2) from chalcopyrite and hexagonal to type near 12 GPa, and (3) to the NaCl type at pressures above 15 GPa. These results confirm the pressure-induced phase transitions indicated by the phonon behavior in a recent high-pressure Raman study of CuGa and AgGa. From the high-pressure x-ray data on the chalcopyrite phase, the following bulk modulus and were obtained by fitting the data to the Murnaghan equation of state: CuGa, , ; , , .
- Received 2 September 1980
DOI:https://doi.org/10.1103/PhysRevB.23.3836
©1981 American Physical Society