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Theoretical study of the vibration-dependent electron anisotropy in O−2 photodetachment

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, , Citation Michal Tarana and Chris H Greene 2012 J. Phys.: Conf. Ser. 388 022105 DOI 10.1088/1742-6596/388/2/022105

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1 Department of Physics and JILA, University of Colorado, Boulder, CO 80309, USA

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1742-6596/388/2/022105

Abstract

Recent experimental works report observations of a significant vibrational dependence of the photoelectron angular distributions (PADs) recorded for the O2(X3Σg) ← O−2 (X2Πg) band. It is the aim of the theoretical model presented here to reproduce the experimental results, allow for a deeper insight into the mechanism of this process and explain the sensitivity of the PAD to vibronic coupling in the anion ground electronic state.

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10.1088/1742-6596/388/2/022105